一种基于电沉积3D花状CoS在自支撑石墨烯胶带电极上的非酶葡萄糖传感器的研究与应用

李江; 李作鹏; 白云峰; 罗宿星; 郭永; 鲍雅妍; 李容; 刘海燕; 冯锋

doi:10.13208/j.electrochem.210421

电化学 >

2022 , Vol. 28 >Issue 1: 2104211

DOI: https://doi.org/10.13208/j.electrochem.210421

论文

一种基于电沉积3D花状CoS在自支撑石墨烯胶带电极上的非酶葡萄糖传感器的研究与应用

李江 ,
李作鹏 ,
白云峰 ,
罗宿星 ,
郭永 ,
鲍雅妍 ,
李容 ,
刘海燕 ,
冯锋

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1.山西大同大学化学与化工学院,山西大同 037009
2.遵义师范学院,贵州遵义 563006
3.西华师范大学化学化工学院,四川南充 637000
4.山西大同大学生命科学院,山西大同 037009

收稿日期: 2021-04-21

修回日期: 2021-06-30

网络出版日期: 2021-08-03

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A Flexible Enzymeless Glucose Sensor via Electrodepositing 3D Flower-like CoS onto Self-Supporting Graphene Tape Electrode

Jiang Li ,
Zuo-Peng Li ,
Yun-Feng Bai ,
Su-Xing Luo ,
Yong Guo ,
Ya-Yan Bao ,
Rong Li ,
Hai-Yan Liu ,
Feng Feng

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1. School of Chemistry and Chemical Engineering, Shanxi Datong University, Datong 037009, Shanxi, P.R. China
2. Department of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi 563006, Guizhou, P.R. China
3. College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637000, Sichuan, P.R. China
4. School of Life and Science, Shanxi Datong University, Datong 037009, Shanxi, P.R. China

* Tel: (86-352)7158662, E-mail: feng-feng64@263.net

Received date: 2021-04-21

Revised date: 2021-06-30

Online published: 2021-08-03

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摘要

本文将3D纳米结构花状CoS电沉积在石墨烯胶带电极（GTE）上,制备了一种对葡萄糖响应良好的电化学传感器。结构分析显示电沉积的CoS均匀地分散在了电极上。实验结果表明,制备的花状CoS/GTE葡萄糖传感器在0.025 ~ 1.0 mmol·L^-1显示出良好的线性关系,灵敏度为323.3 μA·(mmol·L ^-1)^-1·cm^-2,检出限为8.5 μmol·L ^-1 (S/N = 3),而且制备的传感器能够应用于血清葡萄糖的检测。这表明本文制备的传感器具有一定的应用潜力。

关键词： 柔性电极; 花状CoS; 电沉积; 葡萄糖传感器

本文引用格式

李江 , 李作鹏 , 白云峰 , 罗宿星 , 郭永 , 鲍雅妍 , 李容 , 刘海燕 , 冯锋 . 一种基于电沉积3D花状CoS在自支撑石墨烯胶带电极上的非酶葡萄糖传感器的研究与应用[J]. 电化学, 2022 , 28(1) : 2104211 . DOI: 10.13208/j.electrochem.210421

Abstract

Three-dimensional (3D) nanostructural Flower-like cobalt sulfide (CoS) on flexible self-supporting graphene tape electrode (GTE) with remarkably electrocatalytic activity toward glucose was successfully prepared by electrodeposition. Structural characterizations revealed that the electrodeposited CoS was highly dispersed on GTE as an active material. The fabricated binder-free and self-standing CoS/GTE shows a good linear response in the range of 0.025 ~ 1.0 mmol·L^-1, reaching a high glucose sensitivity value of 323.3 μA·(mmol·L ^-1)^-1·cm^-2 and a low detection limit of 8.5 μmol·L ^-1 (S/N = 3). Moreover, the as-prepared sensor was well applied for glucose determination in human serum. Thus, the self-supporting, binder-free, low-cost sensor has good potential as a promising device for practical quantitative analysis of glucose in human serum.

Key words： flexible electrode; flower-like CoS; electrodeposition; glucose sensor

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