固体氧化物电解池直接电解CO2的研究进展
收稿日期: 2019-11-20
修回日期: 2019-11-27
网络出版日期: 2019-12-04
基金资助
国家自然科学基金项目(No. 91645101);国家自然科学基金项目(No. 51972298)
Recent Advances of CO2 Electrochemical Reduction in Solid Oxide Electrolysis Cells
Received date: 2019-11-20
Revised date: 2019-11-27
Online published: 2019-12-04
李一航 , 夏长荣 . 固体氧化物电解池直接电解CO2的研究进展[J]. 电化学, 2020 , 26(2) : 162 -174 . DOI: 10.13208/j.electrochem.191141
Solid oxide electrolysis cells (SOECs) have stimulated wide interests for their promising application in the reduction of CO2 emissions and the storage of renewable energy. Here, the advances made in the development of cathode materials including cermets and perovskite oxides in our research group, are summarized, along with the design of cell configurations. The electrochemical kinetics and performances of cathodes and cells are discussed and analyzed. It is expected that this brief review offers critical insights and useful guidelines for developing superior electrodes and SOECs in the future.
Key words： solid oxide electrolysis cells; CO2 reduction; cathodes; cermets; perovskites
| [1] | Zhang L X, Hu S Q, Zhu X F , et al. Electrochemical reduction of CO2 in solid oxide electrolysis cells[J]. Journal of Energy Chemistry, 2017,26(4):593-601. |
| [2] | Chen L, Chen F L, Xia C R . Direct synjournal of methane from CO2-H2O co-electrolysis in tubular solid oxide electrolysis cells[J]. Energy & Environmental Science, 2014,7(12):4018-4022. |
| [3] | Kondratenko E V, Mul G, Baltrusaitis J , et al. Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes[J]. Energy & Environmental Science, 2013,6(11):3112-3135. |
| [4] | Graves C, Ebbesen S D, Mogensen M , et al. Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy[J]. Renewable and Sustainable Energy Reviews, 2011,15(1):1-23. |
| [5] | Zheng Y, Wang J C, Yu B , et al. A review of high temperature co-electrolysis of H2O and CO2 to produce sustainable fuels using solid oxide electrolysis cells (SOECs): advanced materials and technology[J]. Chemical Society Reviews, 2017,46(5):1427-1463. |
| [6] | Ebbesen S D, Jensen S H, Hauch A , et al. High temperature electrolysis in alkaline cells, solid proton conducting cells, and solid oxide cells[J]. Chemical Reviews, 2014,114(21):10697-10734. |
| [7] | Sridhar K R, Vaniman B T . Oxygen production on Mars using solid oxide electrolysis[J]. Solid State Ionics, 1997,93(3/4):321-328. |
| [8] | Guan J, Doshi R, Lear G , et al. Ceramic oxygen generators with thin-film zirconia electrolytes[J]. Journal of the Ame-rican Ceramic Society, 2002,85(11):2651-2654. |
| [9] | Stempien J P, Liu Q L. Ni, M. , et al. Physical principles for the calculation of equilibrium potential for co-electrolysis of steam and carbon dioxide in a solid oxide electrolyzer cell (SOEC)[J]. Electrochimica Acta, 2014,147:490-497. |
| [10] | Hansen J B . Solid oxide electrolysis - a key enabling technology for sustainable energy scenarios[J]. Faraday Discussions, 2015,182:9-48. |
| [11] | Cheng C Y, Kelsall G H, Kleiminger L . Reduction of CO2 to CO at Cu-ceria-gadolinia (CGO) cathode in solid oxide electrolyser[J]. Journal of Applied Electrochemistry, 2013,43(11):1131-1144. |
| [12] | Wang S J, Inoishi A, Hong J , et al. Ni-Fe bimetallic cathodes for intermediate temperature CO2 electrolyzers using a La0.9Sr0.1Ga0.8Mg0.2O3 electrolyte[J]. Journal of Materials Chemistry A, 2013,1(40):12455-12461. |
| [13] | Wang Y, Liu T, Lei L B , et al. High temperature solid oxide H2O/CO2 co-electrolysis for syngas production[J]. Fuel Processing Technology, 2017,161:248-258. |
| [14] | Zhang Y, Knibbe R, Sunarso J , et al. Recent progress on advanced materials for solid-oxide fuel cells operating below 500 °C[J]. Advanced Materials, 2017,29(48):1700132. |
| [15] | Tao G, Sridhar K R, Chan C L . Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part I. Pt/YSZ interface[J]. Solid State Ionics, 2004,175(1/4):615-619. |
| [16] | Tao G, Sridhar K R, Chan C L . Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part II. Pt-YSZ cermet/YSZ interface[J]. Solid State Ionics, 2004,175(1/4):621-624. |
| [17] | Xie Y M, Xiao J, Liu D D , et al. Electrolysis of carbon dioxide in a solid oxide electrolyzer with silver-gadolinium-doped ceria cathode[J]. Journal of The Electrochemical Society, 2015,162(4):F397-F402. |
| [18] | Green R D, Liu C C, Adler S B . Carbon dioxide reduction on gadolinia-doped ceria cathodes[J]. Solid State Ionics, 2008,179(17/18):647-660. |
| [19] | Ebbesen S D, Mogensen M . Electrolysis of carbon dioxide in solid oxide electrolysis cells[J]. Journal of Power Sources, 2009,193(1):349-358. |
| [20] | Kleiminger L, Li T, Li K , et al. CO2 splitting into CO and O2 in micro-tubular solid oxide electrolysers[J]. RSC Advances, 2014,4(91):50003-50016. |
| [21] | Dong D H, Xu S S, Shao X , et al. Hierarchically ordered porous Ni-based cathode-supported solid oxide electrolysis cells for stable CO2 electrolysis without safe gas[J]. Journal of Materials Chemistry A, 2017,5(46):24098-24102. |
| [22] | Luo Y, Li W Y, Shi Y X , et al. Mechanism for reversible CO/CO2 electrochemical conversion on a patterned nickel electrode[J]. Journal of Power Sources, 2017,366:93-104. |
| [23] | Nepomuceno M A, Kato Y . Development of disk-type solid oxide electrolysis cell for CO2 reduction in an active carbon recycling energy system[J]. Energy Procedia, 2017,131:101-107. |
| [24] | Skafte T L, Blennow P, Hjelm J , et al. Carbon deposition and sulfur poisoning during CO2 electrolysis in nickel-based solid oxide cell electrodes[J]. Journal of Power Sour-ces, 2018,373:54-60. |
| [25] | Song Y F, Zhang X M, Zhou Y J , et al. Promoting oxygen evolution reaction by RuO2 nanoparticles in solid oxide CO2 electrolyzer[J]. Energy Storage Materials, 2018,13:207-214. |
| [26] | Yu L B, Wang J J, Ye Z M , et al. Electrochemical conversion of CO2 over microchanneled cathode supports of solid oxide electrolysis cells[J]. Journal of CO2 Utilization, 2018,26:179-183. |
| [27] | Zheng M H, Wang S, Yang Y , et al. Barium carbonate as a synergistic catalyst for the H2O/CO2 reduction reaction at Ni-yttria stabilized zirconia cathodes for solid oxide electrolysis cells[J]. Journal of Materials Chemistry A, 2018,6(6):2721-2729. |
| [28] | Yu L B, Wang J J, Hu X , et al. A nanocatalyst network for electrochemical reduction of CO2 over microchanneled solid oxide electrolysis cells[J]. Electrochemistry Communications, 2018,86:72-75. |
| [29] | Song Y F, Zhou Z W, Zhang X M , et al. Pure CO2 electrolysis over an Ni/YSZ cathode in a solid oxide electrolysis cell[J]. Journal of Materials Chemistry A, 2018,6(28):13661-13667. |
| [30] | Liu T, Chen X, Wu J J , et al. A highly-performed, dual-layered cathode supported solid oxide electrolysis cell for efficient CO2 electrolysis fabricated by phase inversion co-tape casting method[J]. Journal of The Electrochemical Society, 2017,164(12):F1130-F1135. |
| [31] | Kleiminger L, Kelsall G H, Li T , et al. Effects of current collector materials on performances of micro-tubular solid oxide electrolysers for splitting CO2[J]. High Temperature Experimental Techniques and Measurements, 2015,68(1):3449-3458. |
| [32] | Singh V, Muroyama H, Matsui T , et al. Performance and stability of solid oxide electrolysis cell for CO2 reduction under various operating conditions[J]. Electrochemistry, 2014,82(10):839-844. |
| [33] | Li S S, Li Y X, Gan Y , et al. Electrolysis of H2O and CO2 in an oxygen-ion conducting solid oxide electrolyzer with a La0.2Sr0.8TiO3+δ composite cathode[J]. Journal of Power Sources, 2012,218:244-249. |
| [34] | Li Y X, Zhou J E, Dong D H , et al. Composite fuel electrode La0.2Sr0.8TiO3-δ-Ce0.8Sm0.2O2-δ for electrolysis of CO2 in an oxygen-ion conducting solid oxide electrolyser[J]. Physical Chemistry Chemical Physics, 2012,14(44):15547-15553. |
| [35] | Qi W T, Gan Y, Yin D ., et al. Remarkable chemical adsorption of manganese-doped titanate for direct carbon dioxide electrolysis[J]. Journal of Materials Chemistry A, 2014,2(19):6904-6915. |
| [36] | Xu S S, Li S S, Yao W T , et al. Direct electrolysis of CO2 using an oxygen-ion conducting solid oxide electrolyzer based on La0.75Sr0.25Cr0.5Mn0.5O3-δ electrode[J]. Journal of Power Sources, 2013,230:115-121. |
| [37] | Yue X L, Irvine J T S . (La,Sr)(Cr,Mn)O3/GDC cathode for high temperature steam electrolysis and steam-carbon dioxide co-electrolysis[J]. Solid State Ionics, 2012,225:131-135. |
| [38] | Yue X L, Irvine J T S . Modification of LSCM-GDC cathodes to enhance performance for high temperature CO2 electrolysis using solid oxide electrolysis cells (SOECs)[J]. Journal of Materials Chemistry A, 2017,5(15):7081-7090. |
| [39] | Yang Y, Li Y H, Jiang Y A , et al. The electrochemical performance and CO2 reduction mechanism on strontium doped lanthanum ferrite fuel electrode in solid oxide electrolysis cell[J]. Electrochimica Acta, 2018,284:159-167. |
| [40] | Wang S J, Tsuruta H, Asanuma M , et al. Ni-Fe-La(Sr)Fe-(Mn)O3 as a new active cermet cathode for intermediate-temperature CO2 electrolysis using a LaGaO3-based electrolyte[J]. Advanced Energy Materials, 2015,5(2):1401003. |
| [41] | Tian Y F, Zheng H Y, Zhang L L , et al. Direct electrolysis of CO2 in symmetrical solid oxide electrolysis cell based on La0.6Sr0.4Fe0.8Ni0.2O3-δ electrode[J]. Journal of The Electrochemical Society, 2018,165(2):F17-F23. |
| [42] | Liu SBA, Liu Q X, Luo J L . The excellence of La(Sr)Fe-(Ni)O3 as an active and efficient cathode for direct CO2 electrochemical reduction at elevated temperatures[J]. Journal of Materials Chemistry A, 2017,5(6):2673-2680. |
| [43] | Addo P, Molero-Sanchez B, Chen M , et al. CO/CO2 study of high performance La0.3Sr0.7Fe0.7Cr0.3O3-δ reversible SOFC electrodes[J]. Fuel Cells, 2015,15(5):689-696. |
| [44] | Molero-Sánchez B, Addo P, Buyukaksoy A , et al. Electrochemistry of La0.3Sr0.7Fe0.7Cr0.3O3-δ as an oxygen and fuel electrode for RSOFCs[J]. Faraday Discussions, 2015,182:159-175. |
| [45] | Cao Z Q, Wei B, Miao J P , et al. Efficient electrolysis of CO2 in symmetrical solid oxide electrolysis cell with highly active La0.3Sr0.7Fe0.7Ti0.3O3 electrode material[J]. Electrochemistry Communications, 2016,69:80-83. |
| [46] | Zhou Y J, Zhou Z W, Song Y F , et al. Enhancing CO2 electrolysis performance with vanadium-doped perovskite cathode in solid oxide electrolysis cell[J]. Nano Energy, 2018,50:43-51. |
| [47] | Wang Y, Liu T, Fang S M , et al. Syngas production on a symmetrical solid oxide H2O/CO2 co-electrolysis cell with Sr2Fe1.5Mo0.5O6-Sm0.2Ce0.8O1.9 electrodes[J]. Journal of Power Sources, 2016,305:240-248. |
| [48] | Li Y H, Chen X R, Yang Y , et al. Mixed-conductor Sr2Fe1.5Mo0.5O6-δ as robust fuel electrode for pure CO2 reduction in solid oxide electrolysis cell[J]. ACS Sustainable Chemistry & Engineering, 2017,5(12):11403-11412. |
| [49] | Li Y H, Zou S X, Ju J W , et al. Characteristics of nano-structured SFM infiltrated onto YSZ backbone for symmetrical and reversible solid oxide cells[J]. Solid State Ionics, 2018,319:98-104. |
| [50] | Li Y H, Zhan Z L, Xia C R . Highly efficient electrolysis of pure CO2 with symmetrical nanostructured perovskite electrodes[J]. Catalysis Science & Technology, 2018,8(4):980-984. |
| [51] | Adler S B, Lane J, Steele B . Electrode kinetics of porous mixed-conducting oxygen electrodes[J]. Journal of The Electrochemical Society, 1996,143(11):3554-3564. |
| [52] | Tao S W, Irvine J T S . A redox-stable efficient anode for solid-oxide fuel cells[J]. Nature Materials, 2003,2(5):320-323. |
| [53] | Wang S J, Ishihara T . La0.6Sr0.4Fe0.9Mn0.1O3 oxide cathode for the high temperature CO2 electrolysis using LSGM electrolyte[J]. High Temperature Experimental Techniques and Measurements, 2013,57(1):3171-3176. |
| [54] | Zhang Y Q, Li J H, Sun Y F , et al. Highly active and redox-stable Ce-doped LaSrCrFeO-based cathode catalyst for CO2 SOECs[J]. Acs Applied Materials & Interfaces, 2016,8(10):6457-6463. |
| [55] | Ding D, Li X X, Lai S Y , et al. Enhancing SOFC cathode performance by surface modification through infiltration[J]. Energy & Environmental Science, 2014,7(2):552-575. |
| [56] | Huang H, Lin J, Wang Y L , et al. Facile one-step forming of NiO and yttrium-stabilized zirconia composite anodes with straight open pores for planar solid oxide fuel cell using phase-inversion tape casting method[J]. Journal of Power Sources, 2015,274:1114-1117. |
| [57] | Li Y H, Li P, Hu B B , et al. A nanostructured ceramic fuel electrode for efficient CO2/H2O electrolysis without safe gas[J]. Journal of Materials Chemistry A, 2016,4(23):9236-9243. |
| [58] | Neagu D, Oh T S, Miller D N , et al. Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution[J]. Nature Communications, 2015,6:8120. |
| [59] | Neagu D, Tsekouras G, Miller D N , et al. In situ growth of nanoparticles through control of non-stoichiometry[J]. Nature Chemistry, 2013,5(11):916-923. |
| [60] | Neagu D, Papaioannou E I, Ramli W K W , et al. Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles[J]. Nature Communications, 2017,8(1):1855. |
| [61] | Lai K Y, Manthiram A . Self-regenerating Co-Fe nanoparticles on perovskite oxides as a hydrocarbon fuel oxidation catalyst in solid oxide fuel cells[J]. Chemistry of Materials, 2018,30(8):2515-2525. |
| [62] | Li Y H, Hu B B, Xia C R , et al. A novel fuel electrode enabling direct CO2 electrolysis with excellent and stable cell performance[J]. Journal of Materials Chemistry A, 2017,5(39):20833-20842. |
| [63] | Opitz A K, Nenning A, Rameshan C , et al. Surface chemistry of perovskite-type electrodes during high temperature CO2 electrolysis investigated by operando photoelectron spectroscopy[J]. ACS Applied Materials & Interfaces, 2017,9(41):35847-35860. |
| [64] | Feng Z L A, Machala M L, Chueh W C . Surface electrochemistry of CO2 reduction and CO oxidation on Sm-doped CeO2-x: coupling between Ce 3+ and carbonate adsorbates [J]. Physical Chemistry Chemical Physics, 2015,17(18):12273-12281. |
| [65] | Yu Y, Mao B H, Geller A , et al. CO2 activation and carbonate intermediates: an operando AP-XPS study of CO2 electrolysis reactions on solid oxide electrochemical cells[J]. Physical Chemistry Chemical Physics, 2014,16(23):11633-11639. |
| [66] | Duboviks V, Maher R, Kishimoto M , et al. A Raman spe-ctroscopic study of the carbon deposition mechanism on Ni/CGO electrodes during CO/CO2 electrolysis[J]. Physical Chemistry Chemical Physics, 2014,16(26):13063-13068. |
| [67] | Itoh T, Abe K, Dokko K , et al. In situ Raman spectroelectrochemistry of oxygen species on gold electrodes in high temperature molten carbonate melts[J]. Journal of The Electrochemical Society, 2004,151(12):A2042-A2046. |
/
| 〈 |
|
〉 |
