铂基氧还原催化剂在活性和稳定性方面的挑战

赵拓; 罗二桂; 王显; 葛君杰; 刘长鹏; 邢巍

doi:10.13208/j.electrochem.181205

电化学 >

2020 , Vol. 26 >Issue 1: 84 - 95

DOI: https://doi.org/10.13208/j.electrochem.181205

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铂基氧还原催化剂在活性和稳定性方面的挑战

赵拓 ,
罗二桂 ,
王显 ,
葛君杰 ,
刘长鹏 ,
邢巍

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^1. 中国科学技术大学应用化学与工程学院,安徽合肥 230026
^2. 中国科学院长春应用化学研究所,先进化学电源实验室,电分析化学国家重点实验室,吉林长春 130022

* Tel:（86-431）85262225, E-mail: gejj@ciac.ac.cn;
Tel: （86-431）85262225, E-mail: liuchp@ciac.ac.cn;
Tel: （86-431）85262225, Email: xingwei@ciac.ac.cn

收稿日期: 2018-12-05

修回日期: 2019-01-21

网络出版日期: 2020-02-28

基金资助

国家重点研发计划项目(2017YFB0102900);国家自然科学基金(21633008);国家自然科学基金(21875243);国家自然科学基金(21433003);中国科学院战略重点研究先导项目(XDA09030104);俄罗斯基础研究基金会(18-53-53025);俄罗斯基础研究基金会(Fateev Vladimir);吉林省科技发展项目(20170520150JH);吉林省科技发展项目(20170203003SF);吉林省科技发展项目(20180101030JC)

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Challenges in the Activity and Stability of Pt-Based Catalysts toward ORR

Tuo ZHAO ,
Er-gui LUO ,
Xian WANG ,
Jun-jie GE ,
Chang-peng LIU ,
Wei XING

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^1. School of Applied Chemistry and Engineering University of Science and Technology of China,Hefei 230026, Anhui ,China
^2. State Key Laboratory of Electroanalytica Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences University of Chinese Academy of Sciences, Changchun 130022, Jilin, China

Received date: 2018-12-05

Revised date: 2019-01-21

Online published: 2020-02-28

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摘要

在质子交换膜燃料电池（PEMFC）中,由于阴极氧还原反应（ORR）速率缓慢,因此开发高效的ORR催化剂是实现燃料电池商业化的关键. 世界各地的研究人员在提高催化剂活性和耐久性方面做出了不懈的努力. 目前,铂基催化剂仍然是商业应用上的首选,为开发实用的低铂氧还原催化剂,研究人员开展了大量的研究. 本文说明了ORR反应遇到的挑战,并介绍了近年来铂基氧还原催化剂的研究进展,具体包括ORR机理、铂核壳结构、一维纳米Pt催化剂和其他的代表性工作.

关键词： 铂基催化剂; 氧还原; 铂合金; 核壳结构; 含铂一维结构

本文引用格式

赵拓 , 罗二桂 , 王显 , 葛君杰 , 刘长鹏 , 邢巍 . 铂基氧还原催化剂在活性和稳定性方面的挑战[J]. 电化学, 2020 , 26(1) : 84 -95 . DOI: 10.13208/j.electrochem.181205

Abstract

The development of highly efficient oxygen reduction reaction (ORR) catalysts is the key to the commercialization of fuel cells, where the sluggish ORR reaction rate needs to be overcome by adjusting the intermediates adsorption energies on the catalytic surfaces. To-date, platinum (Pt)-based materials are the-state-of-the-art catalysts in terms of both activity and stability in ORR, making them the preferred choice for commercial applications. However, the high cost of Pt-based catalysts limits their widespread use, leading to massive effects paid in reducing Pt loading, improving catalyst activity and stability. This article illustrates the challenges in the ORR reaction and introduces the recent research progresses in Pt-based oxygen reduction catalysts including the ORR mechanism, core-shell structures, one-dimensional nanostructure, and other representative works of Pt-based catalysts. Some perspectives in the future development trend of Pt-based catalysts are given at the end of the paper, hoping to provide readers with some ideological inspiration.

Key words： Pt-based catalysts; oxygen reduction reaction; platinum alloy; core-shell structures; one-dimensional structure

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