水电解析氢低贵/非贵金属催化剂的研究进展

李阳; 罗兆艳; 葛君杰; 刘长鹏; 邢巍

doi:10.13208/j.electrochem.180855

电化学 >

2018 , Vol. 24 >Issue 6: 572 - 588

DOI: https://doi.org/10.13208/j.electrochem.180855

庆祝衣宝廉院士八十华诞专辑

水电解析氢低贵/非贵金属催化剂的研究进展

李阳 ,
罗兆艳 ,
葛君杰 ,
刘长鹏 ,
邢巍

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1.中国科学院长春应用化学研究所，电分析化学国家重点实验室，吉林省低碳化学电源重点实验室，吉林长春130022；2.中国科学技术大学应用化学与工程学院，安徽合肥 230026

收稿日期: 2018-09-27

修回日期: 2018-10-10

网络出版日期: 2021-12-17

基金资助

国家自然科学基金(No. 21433003, No. 21733004)、中国科学院战略重点研究先导项目(No. XDA21090400, No. XDA09030104)、吉林省科技发展项目(No. 20180101030JC, No. 20170520150JH)资助

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Research Progress in Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts of Water Electrolysis

LI Yang ,
LUO Zhao-yan ,
GE Jun-jie ,
LIU Chang-peng ,
XING Wei

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1.State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power Source, Changchun Institute of Applied Chemistry, Changchun 130022, China; 2.Shcool of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China

Received date: 2018-09-27

Revised date: 2018-10-10

Online published: 2021-12-17

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摘要

氢气作为能量载体的氢能技术由于其清洁性、高能量密度等优势已获得越来越多的青睐与关注. 其中，可持续的产氢技术是未来氢能经济发展的必要先决条件. 通过可再生资源电力驱动的电解水技术是支持氢能经济可持续发展的重要途径，高活性、低成本的析氢催化剂的开发利用是提高水电解技术效率并降低其成本的关键因素. 本文主要介绍了近年来包括低铂催化剂和金属硫化物、金属磷化物、金属硒化物等非铂过渡金属催化剂在析氢方面的研究进展，详细讨论了析氢反应的催化性能、合成方法以及结构?鄄催化性能的关系，最后总结展望了水电解低铂及非铂过渡金属催化剂在未来发展过程中所面临的机遇与挑战.

关键词： 低铂; 非铂; 析氢催化剂; 水电解

本文引用格式

李阳 , 罗兆艳 , 葛君杰 , 刘长鹏 , 邢巍 . 水电解析氢低贵/非贵金属催化剂的研究进展[J]. 电化学, 2018 , 24(6) : 572 -588 . DOI: 10.13208/j.electrochem.180855

Abstract

Hydrogen energy technology with hydrogen as an energy carrier is gaining more and more attention due to its cleanliness and high energy density. Hydrogen fuel cell vehicles have been listed as one of the ultimate energy technologies in the 21st century. Among them, sustainable hydrogen production technology is a necessary prerequisite for the future development of hydrogen energy economy. Electrolyzed water technology driven by renewable resources represents an important way to support the sustainable development of hydrogen energy economy. The development and utilization of high activity, low cost hydrogen evolution catalysts is a key factor in improving the efficiency and reducing the cost of water electrolysis technology. This paper mainly introduces the recent research progress of hydrogen evolution catalysts including low platinum catalysts and non-platinum transition metal catalysts such as metal sulfides metal phosphides, metal selenides, etc; catalytic properties, synthesis methods, and structure-catalytic properties. Finally, the advantages and challenges of water electrolysis low platinum and non-platinum transition metal catalysts in the future development are prospected.

Key words： low Pt; non-Pt; hydrogen evolution catalysts; water electrolysis

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