蚕茧衍生的氮氟共掺杂碳基催化剂在碱性介质中的氧还原电催化性能的研究
收稿日期: 2015-11-26
修回日期: 2015-12-18
网络出版日期: 2016-04-28
基金资助
This work was supported by the National Science Foundation of China (NSFC Project Nos. 21076089, 21276098, 11132004, and U1301245), the Ministry of Science and Technology of China (Project No. 2012AA053402), the Guangdong Natural Science Foundation (Project No. S2012020011061), the Doctoral Fund of the Ministry of Education of China (20110172110012), and the Basic Scientific Foundation of the Central Universities of China (No. 2013ZP0013).
Nitrogen, Fluorine co-doped Silk-derived Carbon for Electrochemical Oxygen Reduction with High Performance in Alkaline Solution
Received date: 2015-11-26
Revised date: 2015-12-18
Online published: 2016-04-28
Supported by
This work was supported by the National Science Foundation of China (NSFC Project Nos. 21076089, 21276098, 11132004, and U1301245), the Ministry of Science and Technology of China (Project No. 2012AA053402), the Guangdong Natural Science Foundation (Project No. S2012020011061), the Doctoral Fund of the Ministry of Education of China (20110172110012), and the Basic Scientific Foundation of the Central Universities of China (No. 2013ZP0013).
刘芳芳 , 彭洪亮 , 廖世军 . 蚕茧衍生的氮氟共掺杂碳基催化剂在碱性介质中的氧还原电催化性能的研究[J]. 电化学, 2016 , 22(2) : 164 -175 . DOI: 10.13208/j.electrochem.151141
A high-performance, doped carbon-based catalyst was synthesized by pyrolyzing hydrothermally treated silkworm cocoon. The effects of preparation conditions and fluorine promotion on various catalysts’ performance were investigated. The catalyst prepared under optimal conditions and doped with nitrogen and fluorine possessed the high specific surface area of more than 1000 m2•g-1 and contained 3.5 and 7.3% (by mass, the same below) N and F, respectively. The activity of the catalyst toward oxygen reduction reaction in an alkaline medium was comparable to that of commercial Pt/C, showing both superior tolerance to methanol poisoning and better durability. Doping with fluorine was found to significantly enhance the performance of catalyst. Possible mechanism for the addition of fluorine is suggested.
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