基于Nafion固定磷钼酸和石墨烯共修饰PEDOT膜电极的电化学过氧化氢传感器
收稿日期: 2015-10-08
修回日期: 2015-11-24
网络出版日期: 2015-12-02
基金资助
国家自然科学基金(No. 21463007，No. 21263002)、广西自然科学基金（No. 2013GXNSFAA019024）和广西教育厅科学技术研究项目（No. 2013YB026）资助
Electrochemical H2O2Sensor Based on the Co-immobilization of Phosphmolybdic Acid and Graphene on PEDOT Film Electrode with Nafion
Received date: 2015-10-08
Revised date: 2015-11-24
Online published: 2015-12-02
以玻碳电极（GCE）为基底电化学聚合制得聚3,4-乙烯二氧噻吩（PEDOT）膜修饰电极，再通过Nafion共固定磷钼酸和石墨烯构建了一种新型的无酶电化学H2O2传感器. 利用扫描电子显微镜（SEM）表征制得的修饰电极，并通过循环伏安法和计时电流法研究了传感器对H2O2的响应性能. 结果表明，在优化条件下，该传感器对H2O2还原具有良好的电催化性能，检测H2O2的线性范围为2.91×10-6 ~ 1.83×10-2 mol•L-1，检出限和灵敏度分别为9.90×10-7 mol•L-1（S/N = 3）和112.5 μA•（mmol•L-1）-1. 此外，该传感器还具有良好的重现性和选择性.
关键词： 电化学H2O2传感器; 聚3,4-乙烯二氧噻吩; 磷钼酸; 石墨烯
周浩贤 , 张俊明 , 屈志宇 , 张潘宇 , 樊友军* . 基于Nafion固定磷钼酸和石墨烯共修饰PEDOT膜电极的电化学过氧化氢传感器[J]. 电化学, 2016 , 22(1) : 57 -63 . DOI: 10.13208/j.electrochem.151008
With a glassy carbon electrode (GCE) as the substrate, the poly(3,4-ethylenedioxythiophene) (PEDOT) film electrode was prepared through the electrochemical polymerization method, then a novel non-enzymatic electrochemical H2O2 sensor was fabricated by co-immobilizing phosphomolybdic acid and graphene with Nafion on the PEDOT/GCE electrode. The modified electrodes were characterized by scanning electron microscopy (SEM), while the responsive properties of the sensor to H2O2 were investigated by cyclic voltammetry and chronoamperometry. The results demonstrated that, under the optimized conditions, the sensor exhibited good electrocatalytic performance for H2O2 reduction. The current response of the sensor was linear to the H2O2 concentration in the range of 2.91×10-6 ~ 1.83×10-2 mol•L-1 with the detection limit and sensitivity being 9.90×10-7 mol•L-1 (S/N = 3) and 112.5 μA•(mmol•L-1)-1, respectively. Moreover, the sensor also exhibited excellent reproducibility and selectivity.
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