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锂离子电池近期研究专辑 (厦门大学 杨勇教授主编)

水热法制备无定形的ZnSnO3/C复合材料及其电化学性能研究

  • 方国清 ,
  • 张瑞雪 ,
  • 刘伟伟 ,
  • 夏丙波 ,
  • 孙洪丹 ,
  • 王海波 ,
  • 吴晶晶 ,
  • 金子信悟 ,
  • 李德成
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  • 苏州大学 化学电源研究所,江苏省锂离子电池材料重点实验室,江苏 苏州 215006

收稿日期: 2013-05-31

  修回日期: 2013-06-28

  网络出版日期: 2013-12-23

Preparation and Electrochemical Properties of Amorphous ZnSnO3/C by Hydrothermally Carbonization Method

  • FANG Guo-Qing ,
  • ZHANG Rui-Xue ,
  • LIU Wei-Wei ,
  • XIA Bing-Bo ,
  • SUN Hong-Dan ,
  • WANG Hai-Bo ,
  • WU Jing-Jing ,
  • KANEKO Shinko ,
  • LI De-Cheng
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  • Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University, Suzhou, 215006, Jiangsu, China

Received date: 2013-05-31

  Revised date: 2013-06-28

  Online published: 2013-12-23

摘要

采用葡萄糖水热碳化法制备了碳包覆无定形的ZnSnO3复合材料(ZnSnO3/C),并利用采用X射线衍射、透射电镜、恒电流充放电测试和交流阻抗技术表征、观察与测试样品的结构、形貌以及电化学性能. 实验结果表明,ZnSnO3/C复合材料具有典型的核壳结构,ZnSnO3/C复合料表现较高的比容量和优异的循环性能,100周期循环比容量仍保持659 mAh·g-1.

本文引用格式

方国清 , 张瑞雪 , 刘伟伟 , 夏丙波 , 孙洪丹 , 王海波 , 吴晶晶 , 金子信悟 , 李德成 . 水热法制备无定形的ZnSnO3/C复合材料及其电化学性能研究[J]. 电化学, 2013 , 19(6) : 571 -574 . DOI: 10.13208/j.electrochem.130358

Abstract

The amorphous ZnSnO3@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO3, the ZnSnO3/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1.

参考文献

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