欢迎访问《电化学(中英文)》期刊官方网站,今天是
环境电化学近期研究专辑(吉林大学 林海波教授主编)

连续电提取浓缩技术

  • 任琼 ,
  • 廖文 ,
  • 吴祖成
展开
  • 浙江大学 能源清洁利用国家重点实验室,环境工程系环境电化学与化学贮能实验室,浙江 杭州310058

收稿日期: 2012-12-25

  修回日期: 2013-03-15

  网络出版日期: 2013-03-15

基金资助

国家自然科学基金项目(No.21073161,No.21173188)资助

Continuous Electroextraction and Concentration Technology

  • REN Qiong ,
  • LIAO Wen ,
  • WU Zu-Cheng
Expand
  • Department of Environmental Ecological Engineering, Zhejiang University, Hangzhou 310058, China

Received date: 2012-12-25

  Revised date: 2013-03-15

  Online published: 2013-03-15

摘要

电去离子技术结合了电渗析和离子交换使离子在树脂中瞬时积累、降低体系电阻、电极上水解产生氢离子与氢氧根离子使树脂在线再生,以去除离子为目的制备纯水和高纯水. 这些被去除的离子在浓室中富集,可发展一种新型浓缩分离提取技术,现已逐渐应用于微量重金属、稀有金属、营养盐、有机酸碱,甚至气体的回收. 本文论述了这一连续电提取浓缩技术的原理及应用并探讨发展趋势,以期引起电化学研究工作者的关注.

本文引用格式

任琼 , 廖文 , 吴祖成 . 连续电提取浓缩技术[J]. 电化学, 2013 , 19(5) : 454 -459 . DOI: 10.61558/2993-074X.2136

Abstract

Electrodeionization process combined electrodialysis with ion exchange provides a method to produce pure water and ultrapure water due to the ions accumulated in the resin instantaneously to reduce the system resistance. Meanwhile, large numbers of hydrogen ions and hydroxyl ions are dissociated by water hydrolysis, thus, the ion exchange resins are in-situ regenerated electrochemically. This technology has been utilized to retrieve useful ions which are enriched in the concentrated compartment from a dilute solution. This hybrid process is consequently developed as a new type of extraction and concentration technology and has been gradually employed in the recoveries of heavy metals, rare metals, nutritive salts, organic acids and alkalis, and even gases. This review describes the principle and future trend of this kind of continuous electroextraction and concentration technology, addressing the applications for attracting attention of scientists in the electrochemistry field.

参考文献

[1] Sirkar K K. Membrane separation technologies: Current developments[J]. Chemical Engineering Communications, 1997, 157(1): 145-184.
[2] Nagarale R K, Gohil G S, Shahi V K. Recent developments on ion-exchange membranes and electro-membrane processes[J]. Advances in Colloid and Interface Science, 2006, 119(2/3): 97-130.
[3] Feng X(冯霄). Concentration and removal of heavy metal ions and nutrient salts from water by EDI[D]. Zhejiang University, 2008.
[4] Bouhidel K E, Lakehal A. Influence of voltage and flow rate on electrodeionization (EDI) process efficiency[J]. Desalination, 2006, 193(1/3): 411-421.
[5] Spoor P B, ter Veen W R, Janssen L J J. Electrodeionization 1: Migration of nickel ions absorbed in a rigid, macroporous cation-exchange resin [J]. Journal of Applied Electrochemistry, 2001, 31(5): 523-530.
[6] Xing Y Q, Chen X M, Wang D H. Electrically regenerated ion exchange for removal and recovery of Cr(VI) from wastewater[J]. Environmental Science and Technology, 2007, 41(4): 1439-1443.
[7] Jonathan W, Joseph G, John A, et al. Production of ultrapure water by continuous electrodeionization[J]. Desalination, 2010, 250(3): 973-976.
[8] Roquebert V, Booth S, Cushing R S. Electrodialysis reversal (EDR) and ion exchange as polishing treatment for perchlorate treatment[J]. Desalination, 2000, 131(1/3): 285-291.
[9] Kuwata M. Electrodeionization apparatus: US, 6274019[P]. 2001-08-14.
[10] Chen X F, Wu Z C. A new configuration of membrane stack for retrieval of nickelabsorbed in resins. Journal of Zhejiang University Science B, 2005, 6(6): 543-545.
[11] Wu Z C(吴祖成), Feng X(冯霄), Chen X F(陈雪芬). A device of electricity recovery of ions and purified water with no scaling and the method: China, CN101007663[P]. 2007-08-01.
[12] Feng X, Wu Z C, Chen X F. Removal of metal ions from electroplating effluent by EDI process and recycle of purified water[J]. Separation and Purification Technology, 2007, 57(2): 257-263.
[13] Johann J, Eigenberger G. Electrodialytic regeneration of ion exchange resin[J]. Chemie Ingenieur Technik, 1993, 65(1): 75-78.
[14] Semmens M J, Dillon C D, Riley C. An evaluation of continuous electrodeionization as an in-line process for plating rinsewater recovery[J]. Environmental Progress, 2001, 20(4): 251-260.
[15] Klischenko R, Kornilovich B, Chebotaryova R, et al. Purification of galvanic sewage from metals by electrodialysis[J]. Desalination, 1999, 126(1/3): 159-162.
[16] Dermentzis K, Christoforidis A, Papadopoulou D, et al. Ion and ionic current sinks for electrodeionization of simulated cadmium plating rinse waters[J]. Environmental Progress & Sustainable Energy, 2011, 30(1): 37-43.
[17] Basta K, Aliane A, Lounis A, et al. Electroextraction of Pb2+ ions from dilute solutions by a process combining ion exchange textiles and membranes[J]. Desalination, 1998, 120(3): 175-184.
[18] Kheira S, Jacqueline S, Jean M, et al. Elimination of nitrate from drinking water by electrochemical membrane processes [J]. Desalination, 1995, 101(2): 123-131.
[19] Kabay N, Yuksel M. removal of nitrate from ground water by a hybrid process combining electrodialysis and ion exchange processes[J]. Separation Science and Technology, 2007, 42(12): 2615-2627.
[20] Meyer N, Parker W J, Van Geel P J, et al. Development of an electrodeionization process for removal of nitrate from drinking water[J]. Desalination, 2005, 175(2): 153-177.
[21] Spiegel E F, Thompson P M, Helden D J, et al. Investigation of an electrodeionization system for the removal of low concentrations of ammonium ions[J]. Desalination, 1999, 123(1): 85-92.
[22] Goffin C, Calay J C. Use of continuous electrodeionization to reduce ammonia concentration in steam generators blow-down of PWR nuclear power plants [J]. Desalination, 2000, 132(1-3): 249-253.
[23] Elleuch M B C, Ben Amor, M, Pourcelly G. Phosphoric acid purification by a membrane process: Electrodeionization on ion-exchange textiles[J].Separation and Purification Technology, 2006, 51(3): 285-290.
[24] Huang C H, Xu T W, Zhang Y P, et al. Application of electrodialysis to the production of organic acids: State-of-the-art and recent developments [J]. Journal of Membrane Science, 2007, 288(1/2): 1-12.
[25] Widiasa I N, Sutrisna P D, Wenten I G. Performance of a novel electrodeionization technique during citric acid recovery[J]. Separation and Purification Technology, 2004, 39(1/2): 89-97.
[26] Lameloise M L, Lewandowski R. Recovering L-malic acid from a beverage industry waste water: Experimental study of the conversion stage using bipolar membrane electrodialysis[J]. Journal of Membrane Science, 2012, 403: 196-202.
[27] Du J J, Lorenz N, Beitle R R, et al. Application of wafer-enhanced electrodeionization in a continuous fermentation process to produce butyric acid with clostridium tyrobutyricum[J]. Separation Science and Technology, 47(1): 43-51.
[28]Takahashi H, Ohba K, Kikuchi K I, et al. Sorption of mono-carboxylic acids by an anion-exchange membrane[J]. Biochemical Engineering Journal, 2003, 16(3): 311-315.
[29]Dean J A. Lange’s Handbook of Chemistry [M]. McGraw-Hill Book Co, New York, 1985.
[30]Wee Y J, Yun J S, Lee Y Y. Recovery of lactic acid by repeated batch electrodialysis and lactic acid production using electrodialysis wastewater[J]. Journal of Bioscience and Bioengineering, 2005, 99(2): 104-108.
[31]Kang M S, Cho S H, Kim S H, et al. Electrodialytic separation characteristics of large molecular organic acid in highly water-swollen cation-exchange membranes[J]. Journal of Membrane Science, 2003, 222(1/2): 149-161.
[32]Takahashi H, Ohba K, Kikuchi K I. Sorption of di- and tricarboxylic acids by an anion-exchange membrane[J]. Journal of Membrane Science, 2003, 222(1/2): 103-111.
[33] Eliseeva T V, Krisilova E V, Chernikov M A. Concentration of basic amino acids by electrodialysis[J]. Chemistry and Materials Science, 2011, 51(8): 626-633.
[34] Eliseeva T V, Tekuchev A Y, Shaposhnik V A, et al. Electrodialysis of amino acid solutions with bipolar ion-exchange membranes[J]. Russian Journal of Electrochemistry, 2001, 37(4): 423-426.
[35] Eliseeva T V, Krisilova E V, Shaposhnik V A. Use of electrodialysis to separate and concentrate gamma-amino butyric acid[J]. Desalination and Water Treatment, 2010, 14(1/3):196-200.
[36] Habe H, Yamano N, Takeda S, et al. Use of electrodialysis to separate and concentrate γ-amino butyric acid [J]. Desalination, 2010, 253(1/3):101-105.
[37] Gurram R N, Datta S, Lin Y J, et al. Removal of enzymatic and fermentation inhibitory compounds from biomass slurries for enhanced biorefinery process efficiencies[J]. Bioresource Technology, 2011, 102(17): 7850-7859.
[38] Boontawan P, Kanchanathawee S, Boontawan A. Extractive fermentation of l-(+)-lactic acid by pediococcus pentosaceus using electrodeionization (EDI) technique[J]. Biochemical Engineering Journal, 2011, 54(3): 192-199.
[39] Willauer H D, DiMascio F, Hardy D R, et al. Development of an electrochemical acidification cell for the recovery of CO2 and H2 from seawater[J]. Industrial & Engineering Chemistry Research, 2011, 50(17), 9876-9882.
文章导航

/