电化学制备有序聚苯胺纳米线阵列

doi:10.61558/2993-074X.2879

电化学（中英文） ›› 2012, Vol. 18 ›› Issue (1): 51-55. doi: 10.61558/2993-074X.2879

电化学制备有序聚苯胺纳米线阵列

高艳新, 孙丽超, 谢素原, 时康*

厦门大学化学化工学院化学系，福建厦门361005

收稿日期:2011-11-04 修回日期:2011-11-14 出版日期:2012-02-28 发布日期:2011-11-30
通讯作者: 时康 E-mail:kshi@xmu.edu.cn
基金资助:
国家自然科学基金（No. 20833005）资助

Electrochemical Fabrication of the Ordered Polyaniline Nanowires Array

GAO Yan-Xin, SUN Li-Chao, XIE Su-Yuan, SHI Kang*

Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Received:2011-11-04 Revised:2011-11-14 Published:2012-02-28 Online:2011-11-30
Contact: SHI Kang E-mail:kshi@xmu.edu.cn

摘要/Abstract

摘要： 以有序碳纳米管阵列电极为基底电极，在硫酸或高氯酸溶液中，分别探明不同电化学聚合方法以及苯胺单体浓度对聚苯胺形貌的影响. 结果表明：采用循环伏安法无法制备出聚苯胺纳米线；而应用恒电位法虽可制得聚苯胺纳米线，但纳米线不能形成有序阵列；只有应用恒电流方法，并且以高浓度苯胺的高氯酸溶液作为聚合溶液，方能制得有序聚苯胺纳米线阵列.

关键词: 电化学聚合法, 碳纳米管阵列, 聚苯胺纳米线阵列

Abstract: The effects of electrochemical fabrication methods in different aniline concentrations on the morphologies of polyaniline, which was polymerized on the aligned-multi-walled carbon nanotubes electrode in H2SO4 or HClO4 electrolyte solution, were investigated. It was demonstrated that the polyaniline nanowires would not be prepared by cyclic voltammotry, whereas the nanowires could be obtained by the potentiostatic method without forming the ordered array. Only when the aniline concentration in HClO4 solution was high enough, the ordered polyaniline nanowires array could be fabricated by the constant current method.

Key words: electrochemical polymerization method, aligned-multi walled carbon nanotubes, polyaniline nanowires array

中图分类号:

TQ035

高艳新, 孙丽超, 谢素原, 时康. 电化学制备有序聚苯胺纳米线阵列[J]. 电化学（中英文）, 2012, 18(1): 51-55.

GAO Yan-Xin, SUN Li-Chao, XIE Su-Yuan, SHI Kang. Electrochemical Fabrication of the Ordered Polyaniline Nanowires Array[J]. Journal of Electrochemistry, 2012, 18(1): 51-55.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.2879

https://electrochem.xmu.edu.cn/CN/Y2012/V18/I1/51

参考文献

[1] Hu L B, Gruner G, Li D, et al. Patternable transparent carbon nanotube films for electrochromic devices [J]. Journal of Applied Physics, 2007, 101(1): 016102.
[2] Tseng R J, Huang J X, Ouyang J Y, et al. Polyaniline nanofiber/gold nanoparticle nonvolatile memory [J]. Nano Letters, 2005, 5(6): 1077-1080.
[3] Liu F J, Huang L M, Wen T C, et al. Composite electrodes eonsisting of platinum particles and polyaniline nanowires as electrocatalysts for methanol oxidation [J]. Polymer Composites, 2007, 28(5): 650-656.
[4] Xu J J, Wang K, Zu S Z, et al. Hierarchical nanocomposites of polyaniline nanowire arrays on graphene oxide sheets with synergistic effect for energy storage [J]. ACS Nano, 2010, 4(9): 5019-5026.
[5] Varela H, Bruno R L, Torreesi R M. Ionic transport in conducting polymers nickel tetrasulfonated phthalocyanine modified electrodes [J]. Polymer, 2003, 44(18): 5369-5379.
[6] Wang J, Torardi C C, Duch M W. Polyaniline-related ion-barrier anticorrosion coatings: II. Protection behavior of polyaniline, cationic, and bipolar films [J]. Synthetic Metals, 2007, 157(21): 851-858.
[7] Forzani E S, Zhang H Q, Nagahara L A. et al. Conducting polymer nanojunction sensor for glucose detection [J]. Nano Letters, 2004, 4(9): 1785-1788.
[8] Zhao M, Wu X M, Cai C X. Polyaniline nanofibers: Synthesis, characterization, and application to direct electron transfer of glucose oxidase [J]. The Journal of Physical Chemistry C, 2009, 113(12): 4987-4996.
[9] Wang Z Y, Liu S N, Wu P, et al. Detection of glucose based on direct electron transfer reaction of glucose oxidase immobilized on highly ordered polyaniline nanotubes [J]. Analytical Chemistry, 2009, 81(4): 1638-1645.
[10] Liu J, Lin Y H, Liang L, et al. Templateless assembly of molecularly aligned conductive polymer nanowires: A new approach for oriented nanostructures [J]. Chemistry - A European Journal, 2003, 9(3): 604-611.
[11] Ma Y F, Zhang J M, Zhao G J, et al. Polyaniline nanowires on Si surfaces fabricated with DNA templates [J]. Journal of the American Chemical Society, 2004, 126(22): 7097-7101.
[12] Lee J I, Cho S H, Park S M, et al. Highly aligned ultrahigh density arrays of conducting polymer nanorods using block copolymer templates [J]. Nano Letters, 2008, 8(8): 2315-2320.

电化学制备有序聚苯胺纳米线阵列

Electrochemical Fabrication of the Ordered Polyaniline Nanowires Array

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

Metrics