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电化学(中英文) ›› 1997, Vol. 3 ›› Issue (1): 40-44. 

• 研究论文 • 上一篇    下一篇

异咯嗪蒙脱石修饰电极的电化学行为

吴志斌,林原,章道道,吴浩青,董绍俊   

  1. 复旦大学化学系,中科院长春应用化学研究所
  • 收稿日期:1997-02-28 修回日期:1997-02-28 出版日期:1997-02-28 发布日期:1997-02-28

Electrochemical Behaviors of Isoalloxazine Confined in Montomorillonite Olay Modified Electrode

Wu Zhibin Lin Yuan Zhang Daodao Wu Haoqin   

  1. (Department of Chemistry, Fudan University, Shanghai 200433) Dong Shaojun (Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun130022
  • Received:1997-02-28 Revised:1997-02-28 Published:1997-02-28 Online:1997-02-28

摘要: 应用十六烷基三甲基溴化铵对蒙脱石进行改性,成功地制备稳定性良好的异咯嗪蒙脱石修饰电极.用循环伏安法对此修饰电极的电化学行为进行了研究,测定了异咯嗪在蒙脱石膜内的化学扩散系数,对异咯嗪在改性蒙脱石中电极反应机制进行了探讨

关键词: 异咯嗪, 蒙脱石, 化学修饰电极

Abstract: A cyclic voltametric investigation of stability and redox properties of isoalloxazne on cetytrimethyammonium bromide(CTAB) modified montomorillonite clay platinium electrode in aqueous solution has been performed. pH dependent film concentrations and apparent diffusion coefficents were measured. The mechanism of the charge transport process with in the clay film were discussed.

Key words: Isoalloxazine, Montomorillonite, Modified electrode

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