摘要:
Field Effect Modulation of Outer-Sphere Electrochemistry at Back-Gated, Ultrathin ZnO Electrodes C.-H. Kim, C. D. Frisbie J. Am. Chem. Soc. DOI: 10.1021/jacs.6b02547 通过场效应调节ZnO薄膜半导体的带沿,从而影响电极/电解质界面的电荷转移速度. 这种场效应对半导体带沿的调控效应可达0.1 ~ 0.4 eV. Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency J. R. Petrie, H. Jeen, S. C. Barron, T. L. Meyer, H. N. Lee J. Am. Chem. Soc. DOI: 10.1021/jacs.6b03520 将SiCoOx薄膜外延生长于各种晶格失配的钙钛矿基底上,利用晶格变形效应调控SiCoOx中的氧缺陷,使其对氧析出反应(OER)的催化活性提高一个数量级,与IrO2催化剂相当.