铁掺杂TiO_2纳米管阵列制备及其光电化学性质

doi:10.61558/2993-074X.1894

电化学（中英文） ›› 2008, Vol. 14 ›› Issue (2): 213-217. doi: 10.61558/2993-074X.1894

铁掺杂TiO_2纳米管阵列制备及其光电化学性质

李静;孙岚;庄惠芳;王成林;杜荣归;林昌健;

厦门大学固体表面物理化学国家重点实验室化学系,厦门大学固体表面物理化学国家重点实验室化学系,厦门大学固体表面物理化学国家重点实验室化学系,厦门大学固体表面物理化学国家重点实验室化学系,厦门大学固体表面物理化学国家重点实验室化学系,厦门大学固体表面物理化学国家重点实验室化学系福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005

收稿日期:2008-05-28 修回日期:2008-05-28 出版日期:2008-05-28 发布日期:2008-05-28

Preparation and Photoelectrochemical Properties of Fe-doped TiO_2 Nanotube Arrays

LI Jing,SUN Lan,ZHUANG Hui-fang,WANG Cheng-lin,DU Rong-gui, LIN Chang-jian

(State Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,Xiamen University,Xiamen 361005,Fujian,China

Received:2008-05-28 Revised:2008-05-28 Published:2008-05-28 Online:2008-05-28

摘要/Abstract

摘要： 应用电化学阳极氧化法,以Fe(NO3)3-HF的混合水溶液作电解液在Ti基底上制备Fe掺杂TiO2纳米管阵列.FESEM、Raman、XPS、DRS等测试表明:经Fe掺杂的TiO2纳米管阵列,管径50~90 nm,管长约200nm.与未掺杂TiO2纳米管阵列相比,前者的紫外可见起始吸收带边随着Fe掺入量的增加而红移;而光电化学性质如光电流也随之显著提高.

关键词: TiO2纳米管阵列, 铁掺杂, 光电化学性质

Abstract: The Fe-doped TiO2 nanotube arrays were fabricated in Fe(NO3)3-HF mixing solutions by electrochemical anodic oxidation method,and characterized by FESEM,Raman,XPS and DRS.The effect of Fe concentratiions on photoelectrochemical property of the arrays was also investigated.The diameters and lengths of Fe-doped TiO2 nanotube arrays were 50~90 nm and about 200 nm,respectively.Compared with the undoped TiO2 nanotube arrays,the absorption edge of Fe-doped TiO2 nanotube arrays appeared red shifting.The more Fe content,the larger red shifting,in addition,the photocurrent of Fe-doped TiO2 nanotube arrays increased obviously.

Key words: TiO2 nanotube arrays, iron dope, photoelectrochemical property

中图分类号:

TB383.1

李静, 孙岚, 庄惠芳, 王成林, 杜荣归, 林昌健, . 铁掺杂TiO_2纳米管阵列制备及其光电化学性质[J]. 电化学（中英文）, 2008, 14(2): 213-217.

LI Jing, SUN Lan, ZHUANG Hui-fang, WANG Cheng-lin, DU Rong-gui, LIN Chang-jian. Preparation and Photoelectrochemical Properties of Fe-doped TiO_2 Nanotube Arrays[J]. Journal of Electrochemistry, 2008, 14(2): 213-217.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.1894

https://electrochem.xmu.edu.cn/CN/Y2008/V14/I2/213

参考文献

[1]Gong D,Grimes C A,Varghese O K,et al.Titaniumoxide nanotube arrays prepared by anodic oxidation[J].J Mater Res,2001,16(12):3331-3334. [2]Fujishima A,Rao T N,Tryk D A.Titanium dixxidephotocatalysis[J].J Photochem Photobiol C-Photo-chem Rev,2000,1(1):1-21. [3]Mor G K,Carvalho M A,Varghese O K,et al.Aroom-temperature TiO2-naotube hydrogen sensor able toselfclean photoactively from environmental contamina-tion[J].J Mater Res,2004,19(2):628-634. [4]Fujishima A,Honda K.Electrochemical photolysis ofwater at a semiconductor electrode[J].Nature,1972,238:37-41. [5]Gratzel M.Dye-sensitisized solar cells[J].J Photo-chem Photobiol C-Photochem Rev,2003,4(2):145-153. [6]Yang B C,Uchida M,Kim H-M,et al.Preparation ofbioactive titanium metal via anodic oxidation treatment[J].Biomaterials,2004,25(6):1003-1010. [7]Ad偄n C,Bahamonde A,Fern偄ndez-Garc姫a M,et al.Stucture and activity of nanonized iron-doped anataseTiO2catalysts for phenol photocatalytic degradation[J].Applied Catalysis B:Environmental,2007,72:11-17. [8]Xin B F,Ren Z Y,Fu HG,et al.Study on the mech-anisms of photoinduced carriers separation and recombi-nation for Fe3+-TiO2photocatalysts[J].Applied Su-face Science,2007,253:4390-4395. [9]Cao Jiang-lin(曹江林),Wu Zu-cheng(吴祖成),Zhang Jian-qing(张鉴清),et al.Cathodic Co-electro-deposition of Fe3+-doped TiO2thin films and their pho-tocatalytic activity under visible light[J].Journal ofInorganic Materials(in Chinese),2007,22:514-518. [10]LAI Yue-ku(赖跃坤),SUN Lan(孙岚),LIN Chang-jian(林昌健),et al.Electrochemical fabrication andformation mechanism of TiO2nanotube arrays on metal-lic titanium surface[J].Acta Phisico-Chimica Sinica(in Chinese),2004,20(9):1063-1066. [11]Ohsaka T,Yamaoka S,Shimomura O.Effect of hudro-static pressur on the Raman spectrum of anatase(TiO2)[J].Solid State Commun,1979,30:345-347. [12]XIAO Mei-qun(肖美群),SHEN Jia-nian(沈嘉年),LI Mou-cheng(李谋成),et al.Effect of Fe~(3+)dopant on absorption spectra and photo catalysis activi-ty of titanium dioxide film[J].Shanghai Metals(inChinese),2004,26(4):13-16.

铁掺杂TiO_2纳米管阵列制备及其光电化学性质

Preparation and Photoelectrochemical Properties of Fe-doped TiO_2 Nanotube Arrays

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 3

Metrics

[1]	林成钢, 林泽泉, 李静, 林昌健. 钴离子(Co2+)掺杂TiO2纳米管阵列的光生阴极保护行为[J]. 电化学（中英文）, 2011, 17(3): 312-317.
[2]	孔丽丽, 林龙翔, 胡融刚, 张帆, 林昌健, . 医用钛表面TiO_2纳米管/HA复合膜层于Tyrode’s生理溶液中电化学腐蚀行为[J]. 电化学（中英文）, 2010, 16(1): 74-78.
[3]	林茂财, 柳东东, 余晴春, 胡鸣若, 屠恒勇, . 甲醇在铁掺杂Pt-ZrO_2/C催化剂上的电氧化[J]. 电化学（中英文）, 2009, 15(2): 216-219.