球磨法制备锌酸钙研究

电化学（中英文） ›› 2005, Vol. 11 ›› Issue (1): 72-76.

球磨法制备锌酸钙研究

李升宪,田拴宝,朱绍山

武汉大学化学与分子科学学院,武汉大学化学与分子科学学院,武汉大学化学与分子科学学院湖北武汉430072 ,湖北武汉430072 ,湖北武汉430072

收稿日期:2005-02-28 修回日期:2005-02-28 出版日期:2005-02-28 发布日期:2005-02-28

Calcium Zincate Prepared by Ball Mill Method

LI Sheng-xian~*,TIAN Shuan-bao,ZHU Shao-shan

(College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China

Received:2005-02-28 Revised:2005-02-28 Published:2005-02-28 Online:2005-02-28

摘要/Abstract

摘要： 应用球磨法制备锌酸钙,并研究制备过程的影响因素.XRD,TG DTA等测试表明,合成的锌酸钙化学组成为Ca(OH)2·2Zn(OH)2·2H2O.粉末微电极和模拟电池实验显示该材料具有良好的循环可逆性.

关键词: 锌酸钙, 二次锌电极, 可充电池, 材料合成

Abstract: Calcium zincate was prepared by ball milling method and the factors that influence its synthesis were investigated. The composition of the compound was Ca(OH)_2·2Zn(OH)_22H_2O, which was verified by XRD and TG-DTA methods. The results of powder microelectrode and in simulated batteries showed that the material had excellent cyclic performance.

Key words: Calcium zincate, Secondary zinc electrode, Rechargeable battery, Material synthesis

中图分类号:

TM911.17

李升宪,田拴宝,朱绍山. 球磨法制备锌酸钙研究[J]. 电化学（中英文）, 2005, 11(1): 72-76.

LI Sheng-xian~*,TIAN Shuan-bao,ZHU Shao-shan. Calcium Zincate Prepared by Ball Mill Method[J]. Journal of Electrochemistry, 2005, 11(1): 72-76.

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