YKI-05缓蚀剂对不同浸没条件下907A钢的缓蚀性能研究

电化学（中英文） ›› 2002, Vol. 8 ›› Issue (4): 439-444.

YKI-05缓蚀剂对不同浸没条件下907A钢的缓蚀性能研究

于辉,吴建华,王洪仁,钱建华,陈光章

七二五研究所青岛分部,七二五研究所青岛分部,七二五研究所青岛分部,七二五研究所青岛分部,七二五研究所青岛分部山东青岛,266071 ,山东青岛,266071 ,山东青岛,266071 ,山东青岛,266071 ,山东青岛,266071

收稿日期:2002-11-28 修回日期:2002-11-28 出版日期:2002-11-28 发布日期:2002-11-28

Studies on The Inhibition of YKI-05 Corrosion Inhibitor to 907A Steel in Different Immersed Environments

YU Hui *, WU Jian-hua,WANG Hong-ren, QIAN Jian-hua, CHEN Guang-zhang

(Qingdao Branch of 725 Institute, Qingdao 266071,China

Received:2002-11-28 Revised:2002-11-28 Published:2002-11-28 Online:2002-11-28

摘要/Abstract

摘要： 利用动电位极化方法 ,研究了有机膦酸醇酯类缓蚀剂 (YKI_0 5 )对 90 7A钢在天然海水中的缓蚀行为 .实验表明 :静态海水中 ,浓度为 30 0mg/L的YKI_0 5缓蚀剂能在 90 7A钢表面形成稳定的缓蚀膜层 ,是一负催化阴极型缓蚀剂 ,于实验周期内其对 90 7A钢的缓蚀效率可稳定在 90 %左右 ;在周期性间歇浸没情况下 ,此种缓蚀剂所形成的膜层很不稳定 ,随着间浸次数的增加 ,膜层破损程度愈甚 ,缓蚀效果减弱 ,缓蚀膜对 90 7A钢表面仅仅是个覆盖层 ,起到抑制了部分阴、阳极反应的作用 ,从而可将缓蚀机制归结为覆盖效应

关键词: YKI-05缓蚀剂, 907A钢, 动电位极化, 缓蚀效率, 缓蚀机制

Abstract: The inhibition of YKI-05 Corrosion inhibitor in different conditions was studied using potentiodynamic polarization technique. The resuled shown that (i) the inhibitor film layer was formed stably on the surface of 907A steel electrode when it was persistently immersed in static seawater and the inhibition efficiency reached 90% or so. The inhibition mechanism is negative catalytic effect. (ii)the inhibitior film layer was not stable when the electrode was periodically immersed in seawater and was destroyed more significantly with the increase of electrode exposing time. The film was only a covered layer on the surface of electrode and it retarded both cathodic and anodic reactions. The inhibition mechanism is blocking effect.

Key words: Inhibitor, 907A steel, Potentiodynamic polarization, Inhibition efficiency, Inhibition mechanism.

中图分类号:

TG172.5

于辉,吴建华,王洪仁,钱建华,陈光章. YKI-05缓蚀剂对不同浸没条件下907A钢的缓蚀性能研究[J]. 电化学（中英文）, 2002, 8(4): 439-444.

YU Hui *, WU Jian-hua,WANG Hong-ren, QIAN Jian-hua, CHEN Guang-zhang . Studies on The Inhibition of YKI-05 Corrosion Inhibitor to 907A Steel in Different Immersed Environments[J]. Journal of Electrochemistry, 2002, 8(4): 439-444.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2002/V8/I4/439

[1]	邓俊豪, 王贵, 胡杰珍, 邓培昌, 胡欢欢. 基于电化学噪声研究模拟海洋大气环境下304不锈钢的点蚀行为[J]. 电化学（中英文）, 2020, 26(2): 298-307.
[2]	刘玉,杜荣归,林昌健. 氯离子对模拟混凝土孔隙液中钢筋腐蚀行为的影响[J]. 电化学（中英文）, 2005, 11(3): 333-336.
[3]	黄令,林克发,杨防祖,许书楷,周绍民. 铜电极表面硅烷膜的自组装及其性能研究[J]. 电化学（中英文）, 2005, 11(2): 188-192.
[4]	张景棠, 叶建弦, 何主亮, 陈克昌. 镍铝介金属镀膜之抗坑蚀行为[J]. 电化学（中英文）, 2003, 9(2): 156-163.
[5]	赵永韬,吴建华,陈范才,高中平,王佳,赵常就. 薄层缓蚀剂液膜对907A钢防蚀效果的电化学测量技术[J]. 电化学（中英文）, 2002, 8(3): 295-300.
[6]	赵永韬, 吴建华, 钱建华, 于辉. 阴极保护和缓蚀剂技术联合保护成膜的阻抗谱研究[J]. 电化学（中英文）, 2000, 6(1): 89-94.