络合沉淀法制备Al取代α-Ni(OH)_2 的正交实验研究

电化学（中英文） ›› 2002, Vol. 8 ›› Issue (1): 54-59.

络合沉淀法制备Al取代α-Ni(OH)_2 的正交实验研究

陈惠,王建明,潘滔,肖慧明,张鉴清

浙江大学化学系,浙江大学化学系,浙江大学化学系,浙江大学化学系,浙江大学化学系浙江杭州310027 ,浙江杭州310027 ,浙江杭州310027 ,浙江杭州310027 ,浙江杭州310027

收稿日期:2002-02-28 修回日期:2002-02-28 出版日期:2002-02-28 发布日期:2002-02-28

Study on the Orthogonal Test of Al-substituted α-Ni(OH)_2 Prepared by Complexation-precipitation Method

CHEN Hui,WANG Jian_ming,PAN Tao,XIAO Hui_ming,ZHANG Jian_qing *

(Dept. of Chem.,Zhejiang Univ.,Hangzhou 310027,China

Received:2002-02-28 Revised:2002-02-28 Published:2002-02-28 Online:2002-02-28

摘要/Abstract

摘要： 通过正交实验研究了影响由络合沉淀法制备的Al取代α_Ni(OH) 2 电化学性能的几个主要因素 .其最佳的合成条件为 :氨水浓度 0 .5mol·L- 1,Al取代含量 15mol% ,pH =11.0 ,在最佳合成条件下制备的样品的最大放电比容量为 30 4mAh·g- 1

关键词: Al取代α_Ni(OH)2, 络合沉淀法

Abstract: Al_substituted α_Ni(OH) 2 was prepared by a complexation_precipitation method and characterized by XRD.The electrochemical performance was tested by the charge_discharge method.The experimental results of orthogonal test showed that the effect order of some key preparative conditions on the electrochemical performance of Al_substituted α_Ni(OH) 2 was the concentration of aqueous ammonia,the content of aluminum and pH value.The optimum prepareative conditions for obtaining the sample with maximum specific discharge capacity(304 mAh·g -1 ) were 0.5 mol·L -1 aqueous ammonia,15 mol% Al content and pH 11.0.

Key words: Al_substituted α_Ni(OH) 2 , Complexation_precipitation, Orthogonal test

中图分类号:

O646

陈惠,王建明,潘滔,肖慧明,张鉴清. 络合沉淀法制备Al取代α-Ni(OH)_2 的正交实验研究[J]. 电化学（中英文）, 2002, 8(1): 54-59.

CHEN Hui,WANG Jian_ming,PAN Tao,XIAO Hui_ming,ZHANG Jian_qing * . Study on the Orthogonal Test of Al-substituted α-Ni(OH)_2 Prepared by Complexation-precipitation Method[J]. Journal of Electrochemistry, 2002, 8(1): 54-59.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2002/V8/I1/54

参考文献

[1]　BodeH ,DehmeltK ,WitteJ .Zurkenntnisdernickelhydroxidelektrode...I .Uberdasnickel(II)_hydroxidhy drat[J].Electrochim.Acta,1996,11:1079. [2]　BarnardR ,RandellCF ,TyeFF .Studiesconcerningchargednickelhydroxideelectrodes.I .Measurementofreversiblepotentials[J].J .Appl.Electrochem.,1980,10:109. [3]　KamathPVishnu,DixitMridula,IndiraL .Stabilizedα_Ni(OH)2 aselectrodematerialforalkalinesecondarcells[J].J .Electrochem.Soc.,1994,141(11):2956. [4]　LengYong_jun,LiuBing,LiaoXiao_zhen,etal.Preparation,structureandelectrochemicalperformanceofalu minum_substitutednickelhydroxidePartIElectrochemical performance[J].ChineseJournalofPowerSources,2000,24(2):77. [5]　XuYan_hui,ChenChangpin.Preliminarystudyonactivematerialα_Ni(OH)2[J].ChineseJournalofPowerSources,1999,23(4):209. [6]　Demourgues_GuerlouLiliane,DelmasClaude.Effectofironontheelectrochemicalpropertiesofthenickelhy droxideelectrode[J].J.Electrochem.Soc.,1994,41(13):713. [7]　LengYong_jun,MaZi_feng,ZhangCun_gen,etal.Preparation,structureandelectrochemicalperformanceofiron_substitutednickelhydroxidesPartIElectrochemicalperformance[J].ChineseJournalofPowerSources,1999,23(6):322. [8]　FaureC ,DelmasC ,FouasierM ,etal.Preparationandcharacterizationofcolbalt_substitutedα_nickelhydroxidestableinKOHmediumPart1.α’_Hydroxidewithanorderedpacking[J].J.PowerSources,1991,35:249. [9]　Guerlou_DemorguesL ,DenageC ,DelmasC .Newmanganese_substitutednickelhydroxidesPart1.Crystalchemistryandphysicalcharacterization[J].J.PowerSources,1994,52:269. [10]　DixitMridula,KamathPVishnu,GopalakrishnanJ .Zinc_substituteda_nickelhydroxideasanelectrodemate rialforalkalinesecondarycells[J].J .Electrochem.Soc.,1999,146(1):79. [11]　LengYong_jun.Preparation,structureandelectrochemicalperformanceofactivematerialsofnickelelectrode[D].Zhejiang:ZhejiangUniversity,1998. [12]　LiRong,YanDa_zhou.PhysicalandelectrochemicalcharacteristicsofNi(OH)2[J].BatteryBimonthly(inchinese),1998,28(2):73. [13]　SugimotoAkiko,IshidaShintaro,HanawaKenzo.PreparationandcharacterizationofNi/Al_layereddoublehydroxide[J].J.Electrochem.Soc.,1999.146(4):1251

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