钙－亚硫酰氯电池的研究

电化学（中英文） ›› 1996, Vol. 2 ›› Issue (1): 79-83.

钙－亚硫酰氯电池的研究

张宝宏，陈猛，王荫东，徐东升

哈尔滨工程大学化工系

收稿日期:1996-02-28 修回日期:1996-02-28 出版日期:1996-02-28 发布日期:1996-02-28

Study of the Calcium-Thionyl Chloride Cells

Zhang Baohong; Chen Meng; Wang Yingdong; Xu Dongsheng

(Department of Chemical Engineering,Harbin Engineering University,Harbin 150001

Received:1996-02-28 Revised:1996-02-28 Published:1996-02-28 Online:1996-02-28

摘要/Abstract

摘要： 应用交流阻抗、恒电流、ＳＥＭ等方法，研究了Ｃａ－ＳＯＣｌ２电池中ＣａＣｌ２（ＳＥＩ）膜的性质；不同电解质和添加剂对电极性能的影响．结果表明，ＣａＣｌ２ＳＥＩ膜在阳极反应时电阻下降。ＣｕＣｌ２、ＣｕＢｒ２可改变ＣａＣｌ２沉积形态，提高阴极性能．组装的Ｃａ－ＳＯＣｌ２电池可高速率放电，在５０ｍＡ·ｃｍ－２的条件下，达到１７．５ｍＡｈ·ｃｍ－２。

关键词: 钙－亚硫酰氯电池, 钙电极, 亚硫酰氯

Abstract: The properties of CaCl_2 SEI covered on the ca electrode surface in thionyl chloride, the influence of various salts in thionyl chloride on the porformance of the Ca anede and carbon cathode, and the function of the additive CuCl_2 and CuBr_2 to cathode in the improvement of the cathode performance were studied by AC impedance, constant current discharge, and SEM. As a result,the Ca-SOCl_2 cell was able to discharge at 50 mA·cm￣(-2)and the capacity reached 17.5 mAh ·cm￣(-2).

Key words: Callcium-thionyl chloride cells, Calcium electrode, Thionyl chloride

中图分类号:

TM911

张宝宏，陈猛，王荫东，徐东升. 钙－亚硫酰氯电池的研究[J]. 电化学（中英文）, 1996, 2(1): 79-83.

Zhang Baohong; Chen Meng; Wang Yingdong; Xu Dongsheng . Study of the Calcium-Thionyl Chloride Cells[J]. Journal of Electrochemistry, 1996, 2(1): 79-83.

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