电化学（中英文） ›› 1996, Vol. 2 ›› Issue (1): 102-106.
• 研究论文 • 上一篇 下一篇
陈彧，黄祖思，蔡瑞芳，章福平
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Chen Yu; Huang Zuen; Cai Ruifang; Zhang Fupin
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摘要： Ｃ_（６０）－ＰＮＶＣ共聚物在溶液中的电化学行为陈，黄祖思，蔡瑞芳，章福平（复旦大学化学系，上海２００４３３）Ｃ６０球状分子内外表面有６０个π电子，组成三维π电子共轭体系，具有很强的三阶非线性、电子亲和力（２．６～２．８ｅＶ）和还原性。可作为优良的电?..
Abstract: The electrochemical behavior of C￣(60)-PNVC copolymer in 1 mol/L LiClO_4-THF solutions has been studied by cyclic voltammetry.The results demonstrated that there are considerable differences of electronic structure between PNVC (Poly (N-vinylcarbazole )) and C￣(60)-PNVC copolymer, this being consistent with the ESR results and the oxidstion-reduction activarion of pure PNVC by C￣(60)-chemical modification. In the potential region,1.3V～-3.5V,five steps,0. 90V/0.60V,0.20V/0.00V,-1.05V/-1.30 V,-1.25V/-1.75 V,-2.00V/-2.50V, of oxidation/reduction proceases were indicated in the cyclic voltammetry for pure PNVC,whereas seven steps,0.20V/0.20V,-0.30V/-0.50 V,-0. 60V/-0.60 V,-0.80V/-1. 10 V,-1.95V/-2. 10 V,-2. 50 V/-2. 70 V,-3. 00V/-3. 00 V, of oxidation/reduction processes for the C￣(60)-PNVC copolymer were observed under the idenrical experimental condirion.
Key words: Poly(N-vinylcarbazole), Polymer, Electrochemical behavior.
中图分类号:
O631.3
陈彧，黄祖思，蔡瑞芳，章福平. C_（60）－PNVC共聚物在溶液中的电化学行为[J]. 电化学（中英文）, 1996, 2(1): 102-106.
Chen Yu; Huang Zuen; Cai Ruifang; Zhang Fupin . The Electrochemical Behavior of C￣(60)-chemically Modified Poly(N-vinylcarhzole)in 1 mol/L LiClO_4-THF Solutions[J]. Journal of Electrochemistry, 1996, 2(1): 102-106.
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https://electrochem.xmu.edu.cn/CN/Y1996/V2/I1/102
