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Scheme 1.
Proposed mechanism for the paired electrochemical syntheses of benzothiophenes
Fig. 3.
Cyclic voltammograms of related compound (5 mmol·L
-1
) in 0.1 mol·L
-1
Bu
4
NBF
4
/DMSO
Table 3. Syntheses of 9-arylphenanthrene derivatives
a,b
Table 2. Syntheses of 2-Arylbenzothiophenea
a
Table 1. Optimization of reaction conditions
a
Fig. 2.
The syntheses of 2-substituted benzothiaphenes
Fig. 1.
Representative structures containing the benzothiophene framework
Fig. 5.
A proposed scheme for obtaining high-performance SSEs from a complex material space of divalent ion SSEs. Data mining will play a key role in capturing promising divalent ion SSE materials as the basis, and an integrated strategy across subsequent data mining, theoretical calculations and modeling, and experiments will be used to reveal the ionic migration mechanism and structure-performance relationships of the potential SSEs. Finally, the ionic migration of these SSEs will be accelerated by considering various optimization strategies.
Fig. 4.
Different anion structures of closo-type materials and halogen analogs. X represents different halogen atoms (F, Cl, Br, and I) [
58
]. Note that halogens’ atomic volumes are larger than the hydrogen atom, and electrostatic potential distribution is more heterogeneous, which could lead to a higher cation ion migration barrier [
60
].
Fig. 3.
Illustration of Mg
2+
migration in ternary spinel MgSc
2
Se
4
. Mg
2+
will overcome an energy barrier to migrate from a to b (i.e., the “tet-oct-tet” pathway). A larger atomic volume is expected to result in a larger triangle plane for a more facile ionic migration.
Fig. 2.
The structure framework of Mg(BH
4
)
2
. (a) Coordination configuration of Mg
2+
and four [BH
4
]
-
. (b) Structure of a cubic Mg(BH
4
)
2
. Mg
2+
is located at the center of a regular tetrahedron constructed by four [BH
4
]
-
anions.
Fig. 1.
Statistics of divalent-ion-conducting materials published during the past 40 years. (a) Distribution of divalent-ion-conducting SSEs as a function of temperature. The right frame shows the counts of SSEs in a diverse range of ionic conductivity. (b) Reports of Mg-, Zn-, and Ca-ion SSEs, where the diverse colors present different SSEs in the upper picture, and the lower picture shows the optimized strategies in Mg-based SSEs.
Fig. 14.
Electrolyte flow velocity distributions of (a) concave-convex structure electrolyte flow velocity distribution, (b) rhombus structure electrolyte flow velocity distribution (c) wedge structure electrolyte flow velocity distribution and (d) expanded mesh structure electrolyte flow velocity distribution; (e) Velocity profile on the transversal line at different y positions on the reference
x
-
y
plane (z = 2.7 mm)
Fig. 13.
Current density distributions with (a) concave-convex structure, (b) rhombus structure, (c) wedge structure and (d) expanded mesh structure
Fig. 12.
Four types of channel structure
I
-
V
curves
Fig. 11.
(a) H
2
distribution in cathode flow path and (b) O
2
distribution in anode flow path
Fig. 10.
(a) Locations of the transversal line for study (
x
-
y
plane,
z
= 2.7 mm); (b) Velocity profile on the transversal line at different y positions on the reference
x
-
y
plane (
z
= 2.7 mm); (c)
x
=0 section flow velocity map; (d)
y
=0 section flow velocity map; (e) Electrolyte flow velocity distribution inside the electrolytic cell; (f) Flow velocity contours
Fig. 9.
(a) Electrolyte current density distribution in bipolar plate concave-convex channel field; (b) Electrolyte current density contour plot
Fig. 8.
Main view of electrode current density at Hz= 2.7 mm (electrode-bipolar plate contact interface)
Fig. 7.
(a) Side view of the current density distribution on the electrodes inside the electrolytic cell (b) Main view of the current density distribution on the electrodes at different height interfaces
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