刻蚀剂对IrO2-MnO2阳极纳米涂层表面形貌及电化学行为的影响

doi:10.13208/j.electrochem.140516

电化学（中英文） ›› 2015, Vol. 21 ›› Issue (1): 91-96. doi: 10.13208/j.electrochem.140516

刻蚀剂对IrO₂-MnO₂阳极纳米涂层表面形貌及电化学行为的影响

范庆国¹，叶志国^1*，孟惠民²，卢春民¹

1. 南昌航空大学材料科学与工程学院，江西南昌 310063；2. 北京科技大学材料科学与工程学院，北京 100083

收稿日期:2014-05-19 修回日期:2014-07-18 出版日期:2015-02-28 发布日期:2014-07-25
通讯作者: 叶志国 E-mail:yezhiguo2008@163.com
基金资助:
国家自然科学基金和航空基金项目（No. 21103085, No. 2013ZF56022）资助

Effects of Etchants on Surface Morphologies and Electrochemical Performance of IrO₂-MnO₂ Anodic Nano-Coatings

FAN Qing-guo¹, YE Zhi-guo^1*, MENG Hui-min², Lu Chun-min¹

1. School of Material Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China; 2. Beijing Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China

Received:2014-05-19 Revised:2014-07-18 Published:2015-02-28 Online:2014-07-25
Contact: YE Zhi-guo E-mail:yezhiguo2008@163.com

摘要/Abstract

摘要： 采用传统热分解法制得了不同刻蚀剂（HCl、H₂SO₄、C₂H₂O₄和HF）处理的Ti基IrO₂-MnO₂纳米涂层阳极，使用场发射扫描电子显微镜（FESEM）、循环伏安（CV）及极化技术等观察和研究各纳米涂层阳极表面形貌及其电化学性能. 结果表明，与HCl和C₂H₂O₄刻蚀剂相比，HF和H₂SO₄刻蚀的基底涂层表面IrO₂纳米颗粒更为密集且尺寸更大；H₂SO₄刻蚀处理的Ti基IrO₂-MnO₂阳极电催化活性最佳，HF次之，C₂H₂O₄再次之，HCl最差.

关键词: 刻蚀剂, IrO₂-MnO₂阳极涂层, 热分解, 循环伏安电荷, 电流密度

Abstract: The IrO₂-MnO₂ anodic nano-coatings were prepared by the traditional thermal decomposition method on the different surfaces of Ti substrates pretreated by different etchants (HCl, H₂SO₄, C₂H₂O₄ and HF). Surface morphologies and electrochemical performance of the Ti based IrO₂-MnO₂ anodic coatings were investigated by field emission scanning electron microscopy (FESEM), cyclic voltammetry (CV) and polarization techniques. Analysis showed that the denser IrO₂ nano-particles with longer dimensions were obtained at the IrO₂-MnO₂ anodic coating surfaces on the Ti substrates etched by HF and H₂SO₄ as compared with those on the Ti substrates etched by HCl and C₂H₂O₄. The decreasing order of electro-catalytic activities for the IrO₂-MnO₂ anodic nano-coatings on the Ti substrates etched by different etchants is H₂SO₄ > HF > C₂H₂O₄ > HCl.

Key words: etchants, IrO₂-MnO₂ coating anode, thermal decomposition, cyclic voltammetric charge, current density

中图分类号:

O646

范庆国，叶志国*，孟惠民，卢春民. 刻蚀剂对IrO₂-MnO₂阳极纳米涂层表面形貌及电化学行为的影响[J]. 电化学（中英文）, 2015, 21(1): 91-96.

FAN Qing-guo, YE Zhi-guo*, MENG Hui-min, Lu Chun-min. Effects of Etchants on Surface Morphologies and Electrochemical Performance of IrO₂-MnO₂ Anodic Nano-Coatings[J]. Journal of Electrochemistry, 2015, 21(1): 91-96.

参考文献

[1]Ye Z G, Meng H M, Chen D, et al. Structure and characteristics of Ti/IrO2(x)+MnO2(1-x) anode for oxygen evolution[J]. Solid State Sciences, 2008, 10(3): 346-354.
[2]Ye Z G, Meng H M, Sun D B. New degradation mechanism of Ti/IrO2+MnO2 anode for oxygen evolution in 0.5M H2SO4 solution[J]. Electrochimica Acta, 2008, 53(18): 5639-5643.
[3]Ye Z G, Meng H M, Sun D B. Electrochemical impedance spectroscopic (EIS) investigation of the oxygen evolution reaction mechanism of Ti/IrO2(x)+MnO2(1-x) electrodes in 0.5M H2SO4 solution[J]. Journal of Electroanalytical Chemistry, 2008, 621(1): 49-54.
[4]Zhou X L, Ye Z G, Hua X Z, et al. Electrocatalytic activity and stability of Ti/IrO2+MnO2 anode in 0.5 M NaCl solution[J]. Journal of Solid State Electrochemistry, 2010, 14(7): 1213-1219.
[5]Bai S J(白少金), Wei Z P(魏宗平), Wang X(王欣), et al. Preparation and performance of novel IrO2-Ta2O5 coated titanium anode with embedded nanoscale IrO2[J]. Transactions of Nonferrous Metals Society of China(中国有色金属学报), 2011, 21(3): 669-674.
[6]Xu H(徐浩), Yan W(延卫), You L(游莉). Effects of various acids treatment on the properties of titanium substrate[J]. Rare Metal Materials and Engineering(稀有金属材料与工程), 2011, 40(9): 1550-1554.
[7]Lamolle S F, Monjo M, Rubert M, et al. The effect of hydro?uoric acid treatment of titanium surface on nanostructural and chemical changes and the growth of MC3T3-E1 cells[J]. Biomaterials, 2009, 30(5): 736-742.
[8]Fóti G, Mousty C, Reid V, Comninellis C. Characterization of DSA type electrodes prepared by rapid thermal decomposition of the metal precursor[J]. Electrochimica Acta, 1998, 44(5): 813-818.
[9]Simon P, Gogotsi Y. Materials for electrochemical capacitors[J]. Nature Materials, 2008, 7(11): 845-854.
[10]Toupin M, Brousse T, Belanger D. Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor[J]. Chemistry of Materials, 2004, 6(16): 3184-3190.
[11]Spinolo G, Ardizzone S, Trasatti S. Surface Characterization of Co3O4 electrodes prepared by the sol-gel method[J]. Journal of Electroanalytical Chemistry, 1997, 423(1): 49-57.
[12]Yeo R S, Orehotsky J, Visscher W, et al. Ruthenium-based mixed oxides as electrocatalysts for oxygen evolution in acid electrolytes[J]. Journal of Electroanalytical Chemistry, 1981, 128(9): 1900-1904.
[13]Li Y J, Chang C C, Wen T C. A mixture design approach to thermally prepared Ir-Pt-Au ternary electrodes for oxygen reduction in alkaline solution[J]. Journal of Applied Electrochemistry, 1997, 27(2): 227
[14]Hu J M, Meng H M, Zhang J Q, et al. Effect of crystallite orientation of IrO2 rutile on the corrosion characteristics of IrO2+Ta2O5 oxide coatings[J]. Journal of Materials Science Letters, 2001, 20(14): 1353-1355.

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刻蚀剂对IrO₂-MnO₂阳极纳米涂层表面形貌及电化学行为的影响

Effects of Etchants on Surface Morphologies and Electrochemical Performance of IrO₂-MnO₂ Anodic Nano-Coatings

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