用导电聚合物(聚吡硌、聚苯胺)与碳纳米管(经酸处理)复合物(ECP-CNT)以及功能添加剂(表面活性剂:苄索氯铵 benzethonium chloride,粘结剂:聚乙烯醇 polyvinyl alcohol)配成水型印泥(aqueous ink),在钛片(厚度:0.1 mm)上网印(screen printing)成所需载量及面积(例如:75 mg cm-2,100 cm2)的均匀的ECP-CNT膜. 以该膜为正极,网印活性炭(pigment black)膜为负极,3.0 mol L-1 KCl 或 1.0 mol L-1 HCl 为电解质,组装不对称超级电容器. 用循环伏安、恒电流充放电、电化学阻抗、光及电显微等方法研究了ECP-CNT复合物、网印膜、单池以及由双极片(bipolar plate)连接的多池堆(multi-cell stack). 以两片印刷面积为100 cm2 的钛双极片组装成三池堆,得到较好的技术指标:堆电压3.0 V,电极电容1.29~1.83 F cm-2,比能量2.30~3.24 Wh kg-1,最大比功率1.04 kW kg-1.
Xiaohang Zhou
,
George Z. Chen
. 钛双极片上网印导电聚合物——碳纳米管复合物及其在水型不对称超级电容器中的电化学性能[J]. 电化学, 2012
, 18(6)
: 548
-565
.
DOI: 10.61558/2993-074X.2623
Composites of conducting polymers (polypyrrole and polyaniline) with acid treated multi-walled carbon nanotubes were formulated into printable aqueous inks, with the aid of functional additives (benzethonium chloride as a surfactant with or without polyvinyl alcohol as a binder). The inks were screen-printed as fairly uniform coatings of various mass loading densities and areas (up to 75 mg cm-2 and 100 cm2) on thin titanium plates (0.1 mm in thickness). These screen-printed plates were used to fabricate both unit cell and multi-cell stack of asymmetrical supercapacitors with screen-printed negative electrodes of activated carbon (pigment black) in aqueous electrolytes (3.0 mol L-1 KCl or 1.0 mol L-1 HCl). In particular, a three-cell stack with two bipolar Ti plates of 100 cm2 in screen-printed area was constructed, demonstrating promising technical specifications: 3.0 V in stack voltage, 1.29~1.83 F cm-2 in electrode capacitance, 2.30~3.24 Wh kg-1 in specific energy, and 1.04 kW kg-1 in maximum specific power. Cyclic voltammetry, galvanostatic charging and discharging, and electrochemical impedance spectrometry were applied to study the composites, screen-printed coatings and individual and bipolarly stacked cells, assisted by optical and electron microscopy.