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化学电源近期研究专辑(武汉大学 杨汉西教授主编)

颗粒粒径与硫酸处理对竹碳电极电化学性能影响的研究

  • 姚煜 ,
  • 余爱水
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  • 复旦大学 上海市分子催化和功能材料重点实验室,化学系,新能源研究院,上海200438

收稿日期: 2011-11-24

  修回日期: 2012-02-17

  网络出版日期: 2012-02-22

基金资助

国家自然科学基金项目(No. 21173054)和上海市分子催化和功能材料重点实验室(No. 08DZ2270500)资助

Influences of Particle Size and Sulfuric Acid Treatment on the Electrochemical Performance of Bamboo Charcoal

  • YAO Yu ,
  • YU Ai-Shui
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  • Department of Chemistry, Institute of New Energy, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, China

Received date: 2011-11-24

  Revised date: 2012-02-17

  Online published: 2012-02-22

摘要

将竹碳进行球磨和硫酸处理,比较颗粒粒径和硫酸处理时间对竹碳电极电化学性能的影响. 结果表明,5 μm平均粒径的竹碳电极具有较好的充放电效率,而硫酸处理可有效提高材料的放电容量,18 h硫酸处理的竹碳电极首次放电比容量可达328.2 mAh?g-1,50次循环后其比容量仍保持302.3 mAh?g-1,显示出优异的循环寿命.

本文引用格式

姚煜 , 余爱水 . 颗粒粒径与硫酸处理对竹碳电极电化学性能影响的研究[J]. 电化学, 2012 , 18(4) : 314 -317 . DOI: 10.61558/2993-074X.2923

Abstract

The bamboo charcoal had been milled and treated by sulfuric acid. The influences of as-prepared material particle size and sulfuric acid treatment on the electrochemical performance had been studied. The result displays that the bamboo charcoal with mean particle size about 5 μm has the best first coulombic efficiency. Sulfuric acid treatment could raise the discharge capacity of bamboo charcoal, and the first discharge capacity of 328.2 mAh.g-1 was obtained with the bamboo charcoal treated by sulfuric acid for 18 h. Furthermore, the capacity of 302.3 mAh.g-1 could be maintained for 50 cycles, showing good cycle performance.
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