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研究论文

表面硅烷化铜箔的电化学腐蚀与防护研究

  • 苗伟俊 ,
  • 张余宝 ,
  • 古宁宇 ,
  • 刘峰
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  • 南昌大学化学系,江西 南昌 330031

收稿日期: 2012-01-13

  修回日期: 2012-02-09

  网络出版日期: 2012-02-24

基金资助

国家自然科学基金(No. 50803026)和江西省科技支撑计划课题(No. 2009BGA00300)资助

Electrochemical Corrosion and Protection of Copper Foil Treated by Surface Siloxane Filming

  • MIAO Wei-Jun ,
  • ZHANG Yu-Bao ,
  • GU Ning-Yu ,
  • LIU Feng
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  • Department of Chemistry, Nanchang University, Nanchang 330031

Received date: 2012-01-13

  Revised date: 2012-02-09

  Online published: 2012-02-24

摘要

用γ-氨丙基三甲氧基硅烷(γ-APS)溶液对铜箔表面硅烷化处理,采用动电位极化和电化学交流阻抗研究不同pH的γ-氨丙基三甲氧基硅烷溶液自组装铜箔电极在0.1 mol.L-1NaCl溶液的腐蚀防护效果,采用扫描电子显微镜观察γ-氨丙基三甲氧基硅烷自组装膜的表面形貌.结果表明,γ-氨丙基三甲氧基硅烷自组装铜箔有较好的腐蚀防护效果,其中pH=7的γ-氨丙基三甲氧基硅烷溶液自组装膜的抗腐蚀效果最佳.

本文引用格式

苗伟俊 , 张余宝 , 古宁宇 , 刘峰 . 表面硅烷化铜箔的电化学腐蚀与防护研究[J]. 电化学, 2012 , 18(4) : 359 -364 . DOI: 10.61558/2993-074X.2931

Abstract

Copper foil specimens were immersed in hydro-alcoholic solution of 3-amino-propyl-trimethoxy-silane (γ-APS) to prepare a protective self-assembled siloxane membrane on the surface. Potentiodynamic polarization and electrochemical impedance spectroscopic tests were performed in 0.1 mol.L-1 NaCl to evaluate the effects of the self-assembled siloxane membranes prepared at different pH of γ-APS on corrosion of copper foil. The surface morphology of siloxane membrane was studied by SEM. Experimental results revealed that the γ-APS self-assembled siloxane membranes effectively inhibited the corrosion of copper foil and the optimum anti-corrosion effect was found when the pH value of the silane solution was 7.
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