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研究简报

电化学动电位再活化法(EPR法)的应用研究

  • 查小琴 ,
  • 梁健 ,
  • 张欣耀 ,
  • 张亚军 ,
  • 张利娟
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  • 中国船舶重工集团公司第七二五研究所,河南,洛阳 471039

收稿日期: 2011-05-11

  修回日期: 2011-05-31

  网络出版日期: 2011-06-09

基金资助

中国船舶重工集团公司第七二五研究所创新课题资助项目(LW080601)

Applied Study of Electrochemical Potentiokinetic Reactivation Method

  • CHA Xiao-Qin ,
  • LIANG Jian ,
  • ZHANG Xin-Yao ,
  • ZHANG Ya-Jun ,
  • ZHANG Li-Juan
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  • Luoyang Ship Material Research Institute, Luoyang 471039, HeNan, china

Received date: 2011-05-11

  Revised date: 2011-05-31

  Online published: 2011-06-09

摘要

应用电化学动电位再活化法(EPR法)评价不锈钢复合板和低铬铁素体不锈钢的晶间腐蚀敏感性. 结果表明,以电化学动电位再活化法测得的反向扫描与正向扫描电流最大值之比(ir / ia)评价堆焊不锈钢复合板00Cr17Ni14Mo2/20R复层晶间敏感性与传统H2SO4-CuSO4-Cu法测定的结果吻合甚好;评价爆炸复合板复层06Cr13R低铬铁素体不锈钢晶间腐蚀敏感性与草酸浸蚀法测定的也一致. 说明该法可以成功用于定量、定性地评价不锈钢复合板和低铬铁素体不锈钢的晶间腐蚀敏感性.

本文引用格式

查小琴 , 梁健 , 张欣耀 , 张亚军 , 张利娟 . 电化学动电位再活化法(EPR法)的应用研究[J]. 电化学, 2011 , 17(3) : 347 -350 . DOI: 10.61558/2993-074X.2853

Abstract

The susceptibility to intergranular corrosion of overlay welding stainless steel composite plate (00Cr17Ni14Mo2) and low-Cr ferritic stainless steel (06Cr13R) was studied by electrochemical potentiokinetic reactivation (EPR) method. The results indicated that the ratio of the maximum current Ir/Ia generated by the reactivation EPR scan to that of the anodic scan is appropriate for evaluating the intergranular corrosion of 00Cr17Ni14Mo2, which is consistent with the H2SO4-CuSO4-Cu method, and also appropriate for evaluating the intergranular corrosion of 06Cr13R, which is consistent with the oxalic acid test method. It shows that the EPR method can be applied to qualitatively and quantitatively evaluate the susceptibility to intergranular corrosion of stainless steel composite plate and low-Cr ferritic stainless steel.

参考文献

[1]GaoZhong-ping(高中平),Chen Fan-cai(陈范才),Zhao Chang-jiu(赵常就).Comparing different criteria of EPR method to evaluate the susceptibility to intergranular corrosion[J]. Journal of Chinese Society for Corrosion and Protection(中国腐蚀与防护学报),2000,20(4):243-247.

[2]Duffault F,Pouzet J P,Lsoombe P. Potentiostatic study of structural modifications caused in a Ni-Cr-Fe alloy by heat treatment at 650℃[J].Corrosion Science,1996,6(2):83-85.

[3]Jin Wei-song(金维松),Lang Yu-ping(郎宇平),Rong Fang(荣凡),Sun Li-jun(孙力军). Research of EPR on the susceptibility to intergranular attack of austenitic stainless steel[J]. Journal of Chinese Society for Corrosion and Protection(中国腐蚀与防护学报),2007,27(1):54-59.

[4]Li Sheng-su(李神速).Examination of sensitization of austenitic stainless steels by double loop EPR test mothod[J].Corrosion Science and Protection Technology(腐蚀科学与防护技术),2000,12(5):288-291.

[5]Wang Feng-ping(王凤平),Kang Wan-li(康万利),Jing He-min(敬和民). Corrosion Electrochemistry Principle、Method and Application[M].Beijing:Chemical Industry Press,2007:24.
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