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研究简报

Ti/Ru0.1Ti0.1Sn0.8O2电极电容性能研究

  • 陈海燕 ,
  • 邵艳群 ,
  • 唐电
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  • 福州大学 材料研究所, 福建 福州 350108

收稿日期: 2011-05-05

  修回日期: 2011-05-05

  网络出版日期: 2011-05-06

基金资助

863项目(2007AA03Z325), 福建省自然科学基金(2009J01239), 福州大学创新团队

Capacitance Behaviors of Ti/Ru0.1Ti0.1Sn0.8O2 Electrodes

  • CHEN Hai-Yan ,
  • SHAO Yan-Qun ,
  • TANG Dian
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  • Institute for Materials Research, Fuzhou University, Fuzhou 350108, China

Received date: 2011-05-05

  Revised date: 2011-05-05

  Online published: 2011-05-06

摘要

低温热分解法制备Ti/Ru0.1Ti0.1Sn0.8O2.XRD表征该样品结构特性,循环伏安和恒流充放电测定电极性能.结果表明,Ti/Ru0.1Ti0.1Sn0.8O2物相属细小的金红石相,在20 mV/s扫速下该电极比电容达933F/g.1000次充放电循环后,比电容衰减23.6﹪,显示良好的循环稳定性和可逆性.

本文引用格式

陈海燕 , 邵艳群 , 唐电 . Ti/Ru0.1Ti0.1Sn0.8O2电极电容性能研究[J]. 电化学, 2011 , 17(2) : 231 -233 . DOI: 10.61558/2993-074X.2835

Abstract

Ti/Ru0.1Ti0.1Sn0.8O2 electrodes were prepared by low temperature thermal decomposition. The structural characteristics were analyzed by X-ray diffraction(XRD).The performances were tested by cyclic voltammetry and constant current charge-discharge measurements. The results show that, the structure of Ti/Ru0.1Ti0.1Sn0.8O2 belongs to small rutile phase. A high specific capacitance of 933F/g is obtained at scan rate of 20 mV/s. The cycle life test shows a 23.6% specific capacitance lost after 1000 cycles. The electrode has a good cycle stability and reversibility.

参考文献

[1] Lin K M, Chang K H, Hu C C, et al. Mesoporous RuO2 for the next generation supercapacitors with an ultrahigh power density[J]. Electrochimica Acta, 2009, 54:4574.

[2] Wen Jian-guo(文建国), Ruan Xiang-yuan(阮湘元), Zhou Zhen-tao(周震涛). Study on preparation and electrochemical pseudocapacitance characteristics of Ru0.1Mn0.9Ox [J]. Rare Metal Materials And Engineering(稀有金属材料与工程), 2009, 38(5): 931-934.

[3] Yuan An-bao(袁安保), Zhang Qing-lin(章庆林). Solid reaction preparation and electrochemical characteristics of nano-structured Co3O4 material for supercapacitor [J]. Journal of Functional Materials and Devices(功能材料与器件学报), 2007, 13(1): 1-6.

[4] Chen Ye(陈野), Liu Liang(刘良), Zhang Zun-bo(张尊波), et al. Preparation of NiO by Parallel Flow Precipitation Process and Its Capacitance Performance [J]. Fine Chemicals(精细化工), 2008, 25(5): 424-427.

[5] Chang K H, Hu C C. Hydrothermal systhesis of Ru-Ti oxides with excellent performances for supercapacitors[J]. Electrochimica Acta, 2006, 52:1749-1757.

[6] Hu C C, Chang K H, Wang C C. Two-step hydrothermal systhesis of Ru-Sn oxide composites for electrochemical supercapacitors[J]. Electrochimica Acta, 2007, 52:4411-4418.

[7] Wang Xin, Tang Dian, Zhou Jin-gen. Microstructure, morphology and electrochemical property of RuO270SnO230mol% and RuO230SnO270mol% coatings[J]. Alloys and Compounds, 2007, 430: 60-66.

[8] Wang Ling-li(王玲利), Peng Qiao(彭乔). Advances in research on Ti anodes coating with RuO2 [J]. Liaoning Chemical Industry(辽宁化工), 2006, 35(8): 486.

[9] Chen Yong-yi(陈永毅), Wang Xin(王欣), Shao Yan-qun(邵艳群), et al. Structure and morphology of titanium anode coating with different combinations from Ru-Ti and Ir-Ta [J]. The Chinese Journal of Nonferrous Metals(中国有色金属学报), 2009, 19(4): 689-694.
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