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研究论文

锌离子在水相介质Zn/V_2O_5二次电池中的迁移性能研究

  • 周家宏
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  • 南京师范大学化学系

收稿日期: 1998-05-28

  修回日期: 1998-05-28

  网络出版日期: 1998-05-28

Studies on the Transport Properties of Zn~2+ in the Zn/V_2O_5 Secondary Battery with Aqueous Medium

  • Zhou Jiahong Xue Kuanhong Pan Guping
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  • (Dept. of Chem., Nanjing Normal University, Nanjing 210097)

Received date: 1998-05-28

  Revised date: 1998-05-28

  Online published: 1998-05-28

摘要

利用间歇性恒电流测定法和XRay衍射法,研究水相介质的Zn/V2O5二次电池中的锌离子在正极材料中的迁移性能及其放电机理;讨论锌离子在正极材料中发生迁移时的某些动力学参数与放电深度的关系.实验结果表明,该电池的正极放电反应为锌离子在ZnxV2O5中的嵌入过程.

本文引用格式

周家宏 . 锌离子在水相介质Zn/V_2O_5二次电池中的迁移性能研究[J]. 电化学, 1998 , 4(2) : 170 -175 . DOI: 10.61558/2993-074X.2691

Abstract

The transport properties and the reaction mechanism of Zn~2+ in the cathode material of Zn/V_2O_5 secondary battery with aqueous medium were studied by use of intermittent titration experiments and X-Ray diffraction analysis. The relations of some kinetic parameters to the discharge depth were discussed. The results of the experiments show that the cathodic discharge reaction is an intercalation process.

参考文献

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