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研究论文

可溶性聚酰亚胺电化学反应机理的研究

  • 朱英邢
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  • 中国科学院长春应用化学所,南京师范大学化学系

收稿日期: 1998-05-28

  修回日期: 1998-05-28

  网络出版日期: 1998-05-28

Study of the Mechanisms of the Electrochemical Reactions of the Soluble Polyimides

  • Zhu Yin Xing Wei Zhao Hui Shi Guizheng Li Yuesheng Ding Mengxian
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  • (Changchun Inst. of Appl. Chem.)Yang Hui Lu Tianhong(Dept. of Chem., Nanjing Normal Univ., Nanjing 210097)

Received date: 1998-05-28

  Revised date: 1998-05-28

  Online published: 1998-05-28

摘要

本文研究了三种可溶性聚酰亚胺(PI)在有机溶剂和水溶液中的电化学行为,发现PI在有机溶剂中的电化学行为明显不同于水溶液.利用红外光谱技术和半经验分子轨道计算方法,结合电化学测试的结果,确证了PI的电化学反应的机理.

本文引用格式

朱英邢 . 可溶性聚酰亚胺电化学反应机理的研究[J]. 电化学, 1998 , 4(2) : 147 -151 . DOI: 10.61558/2993-074X.2688

Abstract

For the first time, the electrochemical behaviors of the three soluble polyimides were studied in the organic and aqueous solutions. It was found that the electrochemical behaviors of PI in the organic solutions are significantly different from that in the aqueous solution. Using the IR spectroscopy and semiempirical molecular orbital calculation and combining the results of the electrochemical measurements, the mechanisms of the electrochemical reactions of polyimides were demonstrated.

参考文献

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