本文报道了细胞色素C在聚乙烯氧化物(PEO)修饰的金电极上的直接电化学行为,发现PEO是细胞色素C电化学反应的促进剂,PEO修饰膜的形态对细胞色素C电化学反应的可逆性有较大的影响.
In this paper, the direct electrochemical reaction of cytochrome c was sudied at the poly (ethylene oxide) film modified gold electrodes. It was found the PEO is a good promoter for the electrochemical reaction of cytochrome c, and the reversibility of reaction of cytochrome c was found to depend on the molecular weight of PEO and the morphology of the PEO films.
1EddowesMJ,HilHAO.Normalmethodfortheinvestigationoftheelectrochemistryofmetaloproteins:cytochromec.J.Chem.Soc.Chem.Commun.,1977:31542ZhangW,SongS,DongS.Heterogeneouselectrontransferofcytochromecfacilitatedbypolypyroleandmethylenebluepolypyrolefilmmodifiedelectrodes.J.Inorg.Biochem.,1990,40:1893CaseliM,MonicaMD,PortacciM.Electrochemicalandspectroscopicstudiesofcytochromecimmoblizedinpolypyrolefilms.J.Electroanal.Chem.,1991,319:3614BartletPN,FaringtonJ.Electrochemistryofcytochromecataconductingpolymerelectrode.J.Electroanal.Chem.,1989,261:4715DeCastroES,HuberEW,VilaroelD,CaliatsatosC,MarkJ,HeinemenWR,MaryT.Electrodewithpolymernetworkfilmsbyiradiationcroslinking.Anal.Chem.,1987,69:1346HendersonRW,RawlinsonWR.Potentiometricandotherstudiesonpreparationsofcytochromecfromox-andhorseheartmuscle.Biochem.,1956,62:217NicholsonRS.Theoryandapplicationofcyclicvoltammetryformeasurementofelectrodereactionkinetics.Anal.Chem.1965,37:1351