固体氧化物燃料电池（ＳＯＦＣ）是八十年代迅速发展起来的新型绿色发电技术，以其能量转化效率高，环境友好，燃料适应性强和寿命长等显著优点，引起许多发达国家的重视．根据１９９７年６月在德国亚琛市举行的第五届固体氧化物燃料电池国际会议交流情况和多年来对ＳＯＦＣ的了解，本文对管式、平板式以及其它新型结构的ＳＯＦＣ电池的最新发展动态作以全面的描述．同时对近两年来ＹＳＺ薄膜型和新型固体电解质中温电池的发展热点也作了全面的介绍
Solid oxide fuel cell(SOFC) is a novel, green electricity generation technology, which has been showing rapid development since 1980's. In light of its high efficiency, environmental friendly, fuel adaptability and long term stability, the Research, Development and Demonstration(RD&D) of this hype of full cell have been emphasized in a large number of developed countries. Based on the information communicated at the latest symposium on SOFC held last year in Aachen(Germany) and the knowledge gained through years of research in this field, a comprehensive review on the latest development of the tubular, this planar SOFC as well as on a number of novel types of SOFC is presented. The research focus and swift development on reduced temperature SOFCs utilizing both YSZ thin films and new electrolytes have been outlined in detail.
1江义，李文钊，王世忠．固体氧化物燃料电池进展．化学进展，1997，9（4）：387～3962MinhNQ．Ceramicfuelcels．J．Am．Ceram．Soc．，1993，76（3）：563～5883HashimotoN．GlobalSOFCactivitiesandevaluationprograms．J．PowerSources，1994，49：103～1144BesseteNF．GeorgeRA．Electrocalperformanceofwestinghouse’sairelectrodesupportedsolidoxidefuelcel，inProc．of2ndInternal．FuelCelConference．Kobe，Japan，1996：267～2705StephenEVTubularSOFCproject，inproc．of2ndInternal．FuelCelConference．KobeJapan，1996：267～2746SinghalSCRecentprogresintubularsolidoxidefuelceltechnology，intheproc．of5thInter．SymposiumonSOFC．Aachen，Germany，1997：37～507KakigamiS，KuriharaTHisatomeNetal，DevelopmentofSOFCmodule，intheproc．of5thinter．SymposiumonSOFC．Aachen，Germany，1997：180～1868DrenckhahnW，GreinerH，IversTifeeE．Materialsforsolidoxidehightemperaturefuelcels，PowerJournal，1994，4：36～389BeieHJ，BlumL，DrenckhahnWetal．SOFCdevelopmentatsiemens，intheProc．of5thInter．SymposiumonSOFC．Aachen，Germany，1997：51～6010MinhNQ，MontgomeryK．PerformanceofreducedtemperatureSOFCstacks，intheproc．of5thInter．SymposiumonSOFC．Aachen，Germany，1997：153～15911WiliamsM．StatusofsolidoxidefuelceldevelopmentinUSA，inproc．ofthe4thInternal．Symp．onSOFC，（ed．DokiyaM．）TheElectrmchemicalSoc．Inc．，NewJersey，1995：10～1912SkakiY，EsakiY，HatoriMetal．Developmentof5kWMOLBtypeSOFC，intheProc．of5thInter，SymposiumonSOFC，Aachen，Germany．1997：61～6813DiethelmR，BrumJ，GamperTetal．，StatusofthesulzerHexissolidoxidefuelcel，intheProc．of5thInter，SymposiumonSOFC．Aachen，Germany，1997：79～8714BuchkremerHP，DiekmannU，HaartLGJde，etal．AdvancesintheanodesupportedplanarSOFCtechnology，intheProc．of5thInter．SymposiumonSOFC．Aachen，Germany，1997：160～17015SelmardeSouza，StevenJVisco，LutgardCDeJonghe．ReducedtemperaturesolidoxidefuelcelbasedonYSZthinfilmelectrolyte．J．Electrochem．Soc．，1997，144（3）：L35～3716TsepinT，PeryE，BarnetS，Lowtemperature．solidoxidefuelcelsutilizingthinbilayerelectrolytes．J．Electrochem．Soc．，1997，144（5）：1130～13217SakkerW，MilekenC，HartrigsenJetal．EvaluationofceriaelectrolytesinSOFCpowerplantapplication，intheProc．of5thInter．SymposimonSOFC．Aachen，Germany，1997：254～26318SahibzadaM，RudkinRASteeleBCHetal，EvaluationofPENstructureincorporatingsupportedthickfilmCe0．9Gd0．1O1．95，intheProc．of5thInter．SymposiumonSOFC．Aachen．Germany，1997：244～25319IshiharaT，MatsudaH，TakitaY，DopedLaGaO3perovskitetypeoxideasanewoxideionicconductor．J．AmChem．Soc．，1994，116：380120IshiharaT，HondaM，NishiguchiHetal，SolidoxidefuelceloperableatdecreasedtemperatureusingLaGaO3perovskiteoxideelectrolyte，intheProc．of5thInter，SymposiumonSOFC．Aachen，Germany，1997：301～31021PonthieuE．SOFCsupportprogramsbytheEuropeanCommision，intheProc．of5thInter．SymposiumonSOFC．Aachen，Germany，1997：12～1922徐志弘，温廷琏，吕之奕．高温燃料电池阴极材料La（Sr）Mno3的导电性能研究．无机材料学报，1994，9（4）：489～49223LianxingHe，TingLianWen，ZhiyiLu．EfectsofaluminafiberinYSZelectrolytemembranesfabricatedbytapecastingintheProc．of1lthInter．Conf．onSolidStateIonics．Hawai，USA，1997：20624JiangYi，YentekakisIV，VayenasCG．Methanetoethylenewith85％yieldinagasrecycleelectrocatalyticreactor＿separator．Science，1994，264：156325JiangYi，KolayannisA，Vayenas．CGHightemperaturecyclicvoltammetryofPtcatalystelectrodesinsolidelectrolytecels．ElectrochimicaActa，1993，38（17）：253326江义，阎景旺，王世忠，于春英，李文钊，平板式氧化物燃料电池（SOFC）研制及性能考察．电化学，1997，3（2）：308～31327JiangYi，WangShizhong，ZhangYahongetal．Kineticstudyoftheformationofoxygenvacancyonlanthanummanganiteelectrodes．J．Electrochem．Soc．，1998，145（2）：373～37828WangShizhong，JiangYi，ZhangYahongetal．TheroleofYSZintheimprovementofelectrochemicalperformanceofYSZ＋LSMcompositeelectrodes．J．Electrochem．Soc．1998，145（32）：1932～193929李道昭，戴学刚等．新型SOFC电池结构．中国专利No．97100771．330马紫峰．固体氧化物燃料电池电催化过程研究〔博士学位论文〕．广州：华南理工大学，1995
