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研究论文

苯在旋转圆盘电极上的氧化过程动力学

  • 张新胜
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  • 华东理工大学联合化学反应工程研究所反应工程国家重点实验室

收稿日期: 1999-02-28

  修回日期: 1999-02-28

  网络出版日期: 1999-02-28

Kinetic Study of Electrooxidation of Benzene

  • Zhang Xinsheng  Ding Ping Dai Yingchun Yuan Weikang
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  • (UNILAB Research. Center of Chem. Reaction Eng., East China Univ. of Sci. and Tech., Shanghai 200237

Received date: 1999-02-28

  Revised date: 1999-02-28

  Online published: 1999-02-28

摘要

Clark等[1]研究苯阳极氧化过程,认为二氧化铅是最合适的电极,苯是二级反应,苯在阳极上首先氧化为产物对苯二醌,产物可进一步氧化成马来酸,直至氧化成二氧化碳.但Ito[2]等研究表明苯阳极氧化还有一个并行反应:苯直接氧化为马来酸.Fleszar和P...

本文引用格式

张新胜 . 苯在旋转圆盘电极上的氧化过程动力学[J]. 电化学, 1999 , 5(1) : 106 -110 . DOI: 10.61558/2993-074X.2718

Abstract

A reaction kinetic study for electrochemical oxidation of benzene was performed on a PbO 2 rotating disk electrode in 1 mol/L H 2SO 4 aqueous solution. The reaction orders, the activation energies and transfer coefficient were measured, and the kinetic expression was obtained.

参考文献

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