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研究论文

摩擦条件下硫脲对1Cr18不锈钢电化学行为的作用

  • 熊金平
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  • 北京化工大学应用化学系,北京科技大学材料科学与工程学院

收稿日期: 1999-05-28

  修回日期: 1999-05-28

  网络出版日期: 1999-05-28

Effect of Inhibitor on Electrochemical Behavior of 1Cr18 Stainless Steel in Acidic Solution under Friction

  • Xiong Jinping
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  • (Dept. of Applied Chem., Beijing Univ. of Chem. Tech., Beijing100029) Sun DongbaiYang Dejun (School of Material Sci. and Eng., Univ. of Sci. and Tech. Beijing, Beijing100083

Received date: 1999-05-28

  Revised date: 1999-05-28

  Online published: 1999-05-28

摘要

控制金属材料的腐蚀或磨损有三种方法:1)合理选用耐蚀金属材料(包括开发新材料或对材料进行适宜的表面强化处理;2)改善金属材料服役的介质环境(包括合理使用缓蚀剂);3)采取电化学保护措施.由于在腐蚀介质中工作的各种摩擦副往往受腐蚀与磨损的协同作用而发生...

本文引用格式

熊金平 . 摩擦条件下硫脲对1Cr18不锈钢电化学行为的作用[J]. 电化学, 1999 , 5(2) : 236 -241 . DOI: 10.61558/2993-074X.3182

Abstract

The electrochemical behavior of 1Cr18 stainless steel had been studied using a reciprocating triboelectrochemical equipment under friction in 0.2 mol/L H2SO4 solution with and without addition of thiourea, the frictionized surface of 1Cr18 stainless steel had been examined by the SEM, XPS and IR. The results showed that the loss rate of 1Cr18 stainless steel in the solution could be reduced by addition of thiourea. The adsorption of thiourea on the surface of 1Cr18 stainless steel prohibited the oxidization of Cr3+ to form Cr() and formation of passive film consisting of CrO42- or/and Cr(), and make the passive range to narrower.

参考文献

1李诗卓等.18-8不锈钢在不同极化电位下的磨损行为.中国腐蚀与防护学报,1988,8(4):2672熊金平.钝性金属材料的摩擦电化学行为:[博士学位论文].北京:北京科技大学,19963曾兆民.实用金属防锈技术.北京:新时代出版社,19864XiongJinpingetal.Efectofinhibitoronrepasivationmechanismof304stainlessteelinchloridesolution.In:procedingoftheinternationalconferenceonsurfacescienceandengineer.Beijing:InternationalAeademicPublishers,1985,3465S.N.Postnikov.Electrophsicalandelectrochemicalphenomenainfriction,cutingandlubrication.Moscow:VanNostrandReiholdCompany,19786D.H.Buckley.Surfaceefectsinadhesion,Friction,WearandLubrication.Amsterdam_Oxford_newYork:Elsevierscientificpublishingcompany,19817E.Rabinowice.Frictionandwearofmaterials.NewYork:Academicpres,19808Kazuo,Nakamoto.Infraredspectraofinorganicandcoordinationcompounds,NewYork,London:JhonWiley&Sons,Inc.,19639熊金平等.1Cr18不锈钢的摩擦电化学行为.腐蚀科学与防护技术,1998,10(3):15510张剑峰.摩擦磨损与抗磨技术.天津:天津科技翻译出版公司,199311李诗卓.添加剂对碳钢腐蚀磨损的影响.中国腐蚀与防护学报,1990,10(3):24512姜晓霞等.腐蚀磨损中添加剂的作用机理初
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