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研究论文

利用充电曲线数据计算钝态金属的腐蚀速度

  • 张远声
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  • 四川轻化工学院化工系!自贡643033,四川轻化工学院化工系!自贡643033

收稿日期: 1999-08-28

  修回日期: 1999-08-28

  网络出版日期: 1999-08-28

Calculation of Corrosion Rate of Passive Metals with Charge Curve Analysis Technique

  • Zhang Yuansheng Gong Min
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  • (Sichuan Inst.of Lignt industry and Chcm.Tech.,Zigong 643033

Received date: 1999-08-28

  Revised date: 1999-08-28

  Online published: 1999-08-28

摘要

对 钝态金 属腐蚀体 系推导了 不含近 似处 理的 充电 曲线 方程 式.提 出 了使 用数 值 微分和线性 回归求 解体系电 化学参数 的计算 机方法.

本文引用格式

张远声 . 利用充电曲线数据计算钝态金属的腐蚀速度[J]. 电化学, 1999 , 5(3) : 294 -296 . DOI: 10.61558/2993-074X.3189

Abstract

This work contains two parts:(1)A charge curve equation having no appro_ximation for passivated metal corrosion systems is derived and compared with the routine charge curve equation,which is virtual only when the polarization is minim(linear range)(2)It is simpler to analyze charge curve data by from of charge differential equation than from charge curve equation.After the charge curve data are measured,the slope of charge curve is computed by numerical differentiation method,then the charge differential equation may be transformed to a set of linear equations using polynomial approximation.The electrochemical parameters of corrosion system would be calculated out from this set of linear equations using regression analysis.The advantage of this method is that there is no restriction of "linear range" and corrosion current density may be gained directly.

参考文献

1   Jons D A, Greene N D. Electroche mical m easure m ent of lo w corrosion rates Corrocion ,1966 ,22(7) :198 2   Aragon p J, Hullbert S F. Use of charge curve analysis technique for In Vivo deter mination of corrosion rates . Corrosion ,1 974 ,30(12) :4 32 3  宋 诗蜇.腐 蚀电化学 研究方法 .北京:化 学工业 出版社,1988 :12 6 4 ?楚南.腐 蚀电化学 原理.北 京:化学工 业出版 社,1 985 :196 5  徐  坚,戴 新民,夏再 筑.腐蚀 金属学及 耐腐蚀 金属材料 .杭州:浙 江科学 技术出版 社,1 981 :254 6  清 华大学, 北京大学《计算方 法》编写组 .计算方 法( 上) .北 京:科学 出版社 ,1981 :4 5
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