欢迎访问《电化学(中英文)》期刊官方网站,今天是
研究论文

新型电活性聚(2,2’-二氨基苯氧基二硫化物)的电化学合成

  • 苏育志 ,
  • 饶燕雯 ,
  • 杨熠 ,
  • 陈梅冰 ,
  • 邱银玲 ,
  • 章永化
展开
  • 广州大学化学系,广州大学化学系,广州大学化学系,广州大学化学系,广州大学化学系,华南理工大学高聚物结构与改性研究室,华南理工大学高聚物结构与改性研究室 广东广州510405 ,广东广州510405 ,广东广州510405 ,广东广州510405 ,广东广州510405 ,广东广州510641 ,广东广州

收稿日期: 2001-11-28

  修回日期: 2001-11-28

  网络出版日期: 2001-11-28

Electrosynthesis of A New Electroactive Poly(2,2'-Diaminophenyloxydisulfide)

  • SU Yu zhi ,
  • RAO Yan wen ,
  • YANG Ye ,
  • CHEN Mei bing ,
  • QIU Yin ling ,
  • ZHANG Yong hua
Expand
  • (1.Dept. of Chem., Guangzhou Univ., Guangzhou,510405 China; 2. Polymer Structure & Modification Research Lab., South China Uni

Received date: 2001-11-28

  Revised date: 2001-11-28

  Online published: 2001-11-28

摘要

在Pt电极上 ,LiClO4 和不同酸的乙腈 /四氢呋喃溶液中 ,通过动电位连续扫描法合成了新型电活性聚 (2 ,2’ -二氨基苯氧基二硫化物 ) (PDAPD) ,研究了电解质LiClO4 及不同酸 (HCl、CF3COOH、CCl3COOH、CH3COOH)的浓度对合成产物的影响 ,实验结果表明 :浓度为 0 .1mol/L的LiClO4 及浓度在 0 .0 5~ 0 .5mol/L之间的HCl是获得高电活性的聚合物导电膜的最佳实验条件

本文引用格式

苏育志 , 饶燕雯 , 杨熠 , 陈梅冰 , 邱银玲 , 章永化 . 新型电活性聚(2,2’-二氨基苯氧基二硫化物)的电化学合成[J]. 电化学, 2001 , 7(4) : 465 -471 . DOI: 10.61558/2993-074X.1440

Abstract

A new electroactive poly(2,2' diaminophenyloxydisulfide) (PDAPD) was successfully synthesized from acetonitrile(AN)/tetrahydrofuran(THF)solutions containing the supporting electrolyte(LiClO 4)and the various kinds of acids(HCl,CF 3COOH,CCl 3COOH) on Pt electrode by consecutive cyclic voltammiry. The effects of the concentrations of supporting electrolyte(LiClO 4) and acid(HCl,CF 3COOH,CCl 3COOH) on electrodepositon of PDAPD film were investigated. The best experimental conditions for electrosynthesis of a highly electroactive conducting polymer film are that the concentrations are 0.1 mol/L and between 0.05 mol/L~0.5 mol/L,respectively for LiClO 4 and HCl.

参考文献

[1] ViscoSJ,DeJongheLC .Ionicconductivityoforganosulfurmeltsforadvancedstorageelectrodes[J].J .Elec trochem.Soc.,1988,135,2905~2909. [2] ViscoSJ,LiuM ,ArmandMB ,etal.Solidredoxpolymerizationelectrodesandtheiruseinall solid statebat teries[J].Mol.Cryst.Liq.cryst.,1990,190,185~195. [3] DoeffMM ,ViscoSJ ,DeJongheLC .Thinfilmrechargeableroomtemperaturebatteriesusingsolidredoxpolymerizationelectrodes[J].J .Electrochem.Soc.,1992,139,1808~1812. [4] NaoiK .AnewconceptofenergystorageArechargeablebatteryusingpolymerization depolymerizationofdisulfidecompounds[J].DenkiKagaku,1993,61,135~136. [5] NaoiK ,OuraY ,IwamizuY .Electrochemistryofdisulfidecompounds:Electrochemicalpolymerization de polymerizationprocessof2,5 dimercapt1,3,4 thiadiazole[J].J .Electrochem.Soc.,1995,142,354~360. [6] OyamaN ,PopeJM ,SotomuraT .Effectsofaddingcopper(Ⅱ)salttoorganosulfurcathodesforrechargeablelithiumbatteries[J].J .Electrochem.Soc.,1997,144,L47L51. [7] MaWenShi,PhDThesis.SouthChinaUviversityofTechnology[J].Guangzhou,1996(inChineses). [8] YuLei,WangXianHong,LiJi,JingXiBing,WangFuSong.Soluble2,5 dimercapto1,3,4 thiadiazole/Poly(otoluidine)electroactivecomposite[J].J .Electrochem.Soc.,1999,146,1712~1716[9] SuYuzhi,ChenMeibing,QiuYinling,GongKecheng.Electrosynthesisofpoly(2,2’ diaminopheny loxydisulfide),Abstractsofthe10th[J].NationalConferenceonElectrochemistry,1999:H033. [10] OsakaT ,OganoS ,NaoiK ,OyamaN .Electrochemicalpolymerizationofelectroactivepolyanilineinnon aqueoussolutionanditsapplicationinrechargeablelithiumbatteries[J].J.Electrochem.Soc.,1989,136,306~309. [11] OsakaT ,NakajimaT ,NaoiK ,OwensBB .Electroactivepolyanilinefilmdepositedfromnonaqueousor ganicmedia[J].J .Electrochem.Soc.,1990,137,2139~2142. [12] YamadaK ,TeshimaK ,KobayashiN .Electropolymerizationofanilinederivativesinnon aqueoussolutionwithoutaprotondonor[J].J.Electroanal.Chem.,1995,394,71~79. [13] GeniesEM ,LaplowskiM ,PenneauLF .Cyclicvoltammetryofpolyaniline:interpretationofthemiddlepeak[J].J .Electroanal.Chem.,1988,249,97~107
文章导航

/