应用交流伏安法和线性电位扫描法研究了Pb ,Pb 1.0at%La和Pb 1.0at%Sm电极在硫酸溶液中以 0 .9V(vs .Hg/Hg2 SO4 )生长的阳极Pb(Ⅱ )膜增长率和膜的阻抗实部变化 ,并采用循环伏安法研究了它们在 0 .6～ 1.6V(vs.Hg/Hg2 SO4 )间的循环伏安特性 ,结果表明 :在铅中添加Sm有利于抑制铅的阳极腐蚀和降低阳极Pb(Ⅱ )膜的阻抗 ,La亦可降低阳极Pb(Ⅱ )膜的阻抗 ,但其作用不如Sm明显
柳厚田
,
杨春晓
,
梁海河
,
杨炯
,
周伟舫
. 铅镧和铅钐合金在硫酸溶液中生长的阳极膜性质的研究[J]. 电化学, 2001
, 7(4)
: 439
-444
.
DOI: 10.61558/2993-074X.3270
AC voltammetry,linear sweep voltammetry,and cyclic voltammetry were applied to study the anodic corrosion of Pb,Pb 1.0at%La and Pb 1.0at%Sm electrodes in 4.5 mol·dm -3 H 2SO 4 solution (25 ℃).The experiment results show that samarium can inhibit the anodic corrosion of lead and decrease the impedance of anodic Pb(Ⅱ) film. Lanthanum can also decrease the impedance of the anodic Pb(Ⅱ)film, but the effect is smaller.
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