应用薄层流动时安法测定电镀废水中铜的含量 .试样溶液由流动状态转换为静止状态时的时库仑电量与铜离子浓度 (2～ 16mg/L)呈良好的线性关系 .对样品溶液进行 8次平行测定的相对标准偏差小于 0 .1% ,标准加入法测定的回收率为 99%～ 10 3% .该方法克服了电容电流及电极表面性质改变等噪声干扰 ,具有快速灵敏、准确、再现性好的优点

The chronocoulometry for flowing solution was devoloped and applied to the detemination of copper(Ⅱ) in the waste water of plating.The linear range of copper(Ⅱ) was 2～16mg/L,and the relative standard deviation was less than 0.1% ( n =8).The recovery was 98%～103% for copper(Ⅱ) in the waste water.Chronocoulometry for flowing solution overcomed noise disturbance resulting from capacity current and variety of property of electrode surface.This method was sensitive,accurate and well reproducible.