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研究论文

二苯并18冠6促进钾离子在微液-液界面上的迁移反应

  • 詹东平 ,
  • 吴秉亮
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  • 武汉大学化学与分子科学学院,武汉大学化学与分子科学学院 湖北武汉430072 ,湖北武汉430072

收稿日期: 2002-08-28

  修回日期: 2002-08-28

  网络出版日期: 2002-08-28

Facilitated K~+ ion transfer by DB18C6 across the micro Liquid/Liquid interface

  • ZHAN Dong_ping ,
  • WU Bing_liang
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  • (Collega of Chemistry & Molecule Science, Wuhan University, Wuhan 430072, China

Received date: 2002-08-28

  Revised date: 2002-08-28

  Online published: 2002-08-28

摘要

本文研制出一种用于构造互不相溶电解质界面 (ITIES)的两亲性微孔电极 ,并对发生于该界面上的二苯并 18冠 6 (DB18C6 )促进钾离子的迁移反应进行了研究 ,计算其相关的反应参数 .实验证明 ,该方法操作简便 ,是研究ITIES界面上电荷迁移反应的一种有效工具

本文引用格式

詹东平 , 吴秉亮 . 二苯并18冠6促进钾离子在微液-液界面上的迁移反应[J]. 电化学, 2002 , 8(3) : 252 -256 . DOI: 10.61558/2993-074X.1460

Abstract

A novel microcavity Ag|AgCl electrode was fabricated to construct the micro_interface of two immiscible electrolyte solutions(ITIES). The transfer reactions of K + ion facilitated by DB18C6 across the water/1,2_DCE interface was investigated with the three_electrodes system. The corresponding reaction parameters were derived from the voltammetric data. The results showed that the microcavity electrode would be a useful and efficient tool to investigate the charge transfer reactions at ITIES.

参考文献

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