本文研制出一种用于构造互不相溶电解质界面 (ITIES)的两亲性微孔电极 ,并对发生于该界面上的二苯并 18冠 6 (DB18C6 )促进钾离子的迁移反应进行了研究 ,计算其相关的反应参数 .实验证明 ,该方法操作简便 ,是研究ITIES界面上电荷迁移反应的一种有效工具

A novel microcavity Ag|AgCl electrode was fabricated to construct the micro_interface of two immiscible electrolyte solutions(ITIES). The transfer reactions of K + ion facilitated by DB18C6 across the water/1,2_DCE interface was investigated with the three_electrodes system. The corresponding reaction parameters were derived from the voltammetric data. The results showed that the microcavity electrode would be a useful and efficient tool to investigate the charge transfer reactions at ITIES.