综述了质子交换膜燃料电池 (PEMFC)数学模型的研究进展 ,分析PEMFC中膜、催化层、扩散层和流场区域的传递现象和水、热管理的重要性 ,讨论了模型的维数、复杂性和求解方法 .提出了带有时间维数的PEMFC模型研究的实际应用意义
In the review with 49 references, the mathematical models for proton exchange membrane fuel cell (PEMFC) were summarized. The mechanistic model and empirical model were introduced. Transfer in the membrane, catalyst layer,diffusion layer and flow field of PEMFC were described. The importance of water and heat management was analyzed. The dimension, complexity and solving methods of the PEMFC model were discussed. The importance and validity to develop a model with time dimension are put forward.
[1] RastlerD .Challengesforfuelcellsasstationarypowerresourceintheevolvingenergyenterprise[J].J .PowerSources,2000,86:34.
[2] YiBL ,HanM ,ZhangEJ ,etal.1kWprotonexchangemembranefuelcellstack[J].ChineseJournalofPow erSources,1999,23(2):120.
[3] ChoiKH ,PeckDH ,KimCS ,etal.WatertransportinpolymermembranesforPEMFC[J].J .PowerSources,2000,86(1_2):197.
[4] SoneY ,EkdungeP ,SimonssonD .ProtonconductivityofNafion117asmeasuredbyafour_electrodeACimpedancemethod[J].J .Electrochem.Soc.,1996,143(4):1254.
[5] BuchiFN ,SchererGG .InvestigationofthetransversalwaterprofileinNafionmembranesinpolymerelec trolytefuelcell[J].J .Electrochem.Soc.,2001,148(3):A183.
[6] BernardiDM ,VerbruggeMW .Amathematicalmodelofthesolid_polymer_electrolytefuelcells[J].J.Elec trochem.Soc.,1992,139(9):2477.
[7] EikerlingM ,KharkatsYI ,KornyshevAA ,etal.Phenomenologicaltheoryofelectro_osmoticeffectandwatermanagementinpolymerelectrolyteproton_conductingmembranes[J].J .Electrochem.Soc.,1998,145(8):2684.
[8] ThampanT ,MalhotraS ,TangH ,etal.Modelingofconductivetransportinproton_exchangemembranesforfuelcells[J].J .Electrochem.Soc.,2000,147(9):3242.
[9] PaddisonSJ,PaulR ,ZawodzinsiTA .Astatisticalmechanicalmodelofprotonandwatertransportinaprotonexchangemembrane[J].J .Electrochem.Soc.,2000,147(2):617.
[10] GeSH ,YiBL ,XuHF .Modelofwatertransportforproton_exchangemembranefuelcell[J].Journalofchemicalindustryandengineering(China),1999,50(1):39.
[11] WilsonMS ,ValerioJA ,GottesfeldS .Lowplatinumloadingelectrodesforpolymerelectrolytefuelcellsfab ricatedusingthermoplasticionomers[J].Electrochem.Acta,1995,40:355.
[12] BultelY ,OzilP ,DurandR .ModelingthemodeofoperationofPEMFCelectrodesattheparticlelevel:influ enceofohmicdropwiththeactivelayeronelectrodeperformance[J].J .Appl.Electrochem.,1998,28:269.
[13] BernardiDM ,VerbruggeMW .Mathematicalmodelofagasdiffusionelectrodebondedtoapolymerelec trolyte[J].AIChEJ.,1001,37(8):1151.
[14] BeversD ,WohrM ,YasudaK ,etal.Simulationofapolymerelectrolytefuelcellelectrode[J].J .Appe.Elec trochem.,1997,27:1254.
[15] YouL ,LiuH .AparametricstudyofthecathodecatalystlayerofPEMfuelcellsusingapseudo_homogeneousmode[J].Inter.JHydrogenEnergy,2001,26:991.
[16] ChanSH ,TunWA .Catalystlayermodelsforprotonexchangemembranefuelcells[J].Chem.Eng.Tech nol.,2001,24(1):51.
[17] BrokaK ,EkdungeP .ModelingthePEMfuelcellcathode[J].J .Appl.Electrochem.,1997,27:281.
[18] PerryML ,NewmanJ,CairnsEJ .Masstransportingas_diffusionelectrodes:adiagnostictoolforfuel_cellcathodes[J].J .Electrochem.Soc.,1998,145(1):5.
[19] RhoYW ,SrinivasanS ,KhoYT .MasstransportphenomenainprotonexchangemembranefuelcellsusingO2/He,O2/ArandO2/N2 mixtures,Ⅱ.Theoreticalanalysis[J].J.Electrochem.Soc.,1994,14(8):2089.
[20] SpringerTE ,RaistrickID .Electricalimpedanceofaporewallfortheflooded_agglomeratemodelofporousgas_diffusionelectrodes[J].J.Electrochem.Soc.,1989,136(6):1594.
[21] JordanLR ,ShuklaAK ,BehrsingT ,etal.Diffusionlayerparametersinfluencingoptimalfuelcellperfor mance[J].J .PowerSources,2000,86(1_2):250.
[22] YiJS ,NguyenTV .Multicomponenttransportinporouselectrodesofprotonexchangemembranefuelcellsusingtheinterdigitatedgasdistributors[J].J .Electrochem.Soc.,1999,146(1):38.
[23] NguyenTV ,WhiteRE .Awaterandheatmanagementmodelforproton_exchange_membranefuelcells[J].J.Electrochem.Soc.,1993,140(8):2178.
[24] SpringerTE ,WilsonMS ,GottesfeldS .Modelingandexperimentaldiagnosticsinpolymerelectrolytefuelcell[J].J.Electrochem.Soc.,1993,140(12):3513.
[25] WangZH ,WangCY ,ChenKS .Two_phaseflowandtransportintheaircathodeofprotonexchangemem branefuelcells[J].J .PowerSources,2001,94(1):40.
[26] ThirumalaiD ,WhiteRE .Mathematicalmodelingofproton_exchange_membranefuel_cellstacks[J].J .Elec trochem.Soc.,1997,144(5):1717.
[27] BernardiDM .Water_blancecalculationsforsolid_polymer_electrolytefuelcells[J].J .Electrochem.Soc.,1990,137(11):3344.
[28] SpringerTE ,ZawodzinskiTA ,GottesfeldS .Polymerelectrolytefuelcellmode[J].J .Electrochem.Soc.,1991,138(8):2334.
[29] FullerTF ,NewmanJ.Waterandthermalmanagementinsolid_polymer_electrolytefuelcells[J
