锆基非晶质合金在300～500℃空气中之氧化行为研究

谢心心; 开物; 聂台刚; 河村能人

doi:10.61558/2993-074X.1498

电化学 >

2003 , Vol. 9 >Issue 2: 147 - 155

DOI: https://doi.org/10.61558/2993-074X.1498

研究论文

锆基非晶质合金在300～500℃空气中之氧化行为研究

谢心心 ,
开物 ,
聂台刚 ,
河村能人

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台湾海洋大学材料工程研究所,台湾海洋大学材料工程研究所,劳伦斯利物浦国家实验室,熊本大学工学部熊本台湾基隆20224 ,台湾基隆20224 ,L.3 50 ,P. O. Box利物浦CA94511 ,美国 ,860-8555日本

收稿日期: 2003-05-28

修回日期: 2003-05-28

网络出版日期: 2003-05-28

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Oxidation Behavior of Zr-Cu-Al-Ni Amorphous Alloys in Air at 300～500 ℃

H. H. Hsieh ,
W. Kai ,
T. G. Neih ,
Y. Kawamura

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( 1.Institute of Materials Engineering,Taiwan Ocean University,Keelung,20224,Taiwan,China,2.Lawrence Livermore National Laboratory, L_350, P. O. Box, Livermore, CA94551, USA,3.Department of Mechanical Engineering and Materials Science, Kumamoto University, Kumamoto 860_8555, Japan)

Received date: 2003-05-28

Revised date: 2003-05-28

Online published: 2003-05-28

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摘要

本研究探讨锆基块状非晶质材料(Zr＿30Cu＿10Al＿5Ni)在空气中于300～500℃下之氧化行为.结果显示,非晶质合金之腐蚀动力学在300℃表现为直线型规律,350～425℃遵从抛物线型规律且氧化速率随温度上升呈现相对下降的趋势,但500℃时呈现复杂而不规则氧化行为.此外,非晶质合金氧化后生成的氧化物在300℃下皆为正方晶之ZrO2,当温度T≥350℃时,以正方晶结构之ZrO2为主,单斜晶之ZrO2和CuO次之.

关键词： 锆基非晶质材料; 氧化行为; 腐蚀动力学; ZrO2; CuO

本文引用格式

谢心心 , 开物 , 聂台刚 , 河村能人 . 锆基非晶质合金在300～500℃空气中之氧化行为研究[J]. 电化学, 2003 , 9(2) : 147 -155 . DOI: 10.61558/2993-074X.1498

Abstract

The oxidation behavior of the Zr_based bulk amorphous alloy (BMG; Zr_30Cu_10Al_5Ni in at.%) was studied in dry air over the temperature range 300～500 ℃. The kinetic results indicated that the amorphous alloy oxidized linearly at 300 ℃,while the parabolic oxidation was observed at 350～425 ℃, and the oxidation behavior at 500 ℃ was irregular and complicated. In general, the scales formed on the surface of the amorphous alloy were temperature_dependent, consisting of tetragonal_ZrO2 at 300　℃, and of mostly tetragonal_ZrO2 as well as minor amounts of monoclinic_ZrO2 and CuO at T≥350　℃.

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