欢迎访问《电化学(中英文)》期刊官方网站,今天是
研究论文

铝合金稀土转化膜成膜工艺研究

  • 王均涛 ,
  • 吴建华 ,
  • 陈光章
展开
  • 七二五研究所青岛分部,七二五研究所青岛分部,七二五研究所青岛分部 山东青岛266071 ,山东青岛266071 ,山东青岛266071

收稿日期: 2003-08-28

  修回日期: 2003-08-28

  网络出版日期: 2003-08-28

The Technique of Rare-earth Conversion Coatings on Aluminum Alloy

  • WANG Jun_tao ,
  • WU Jian_hua ,
  • CHEN Guang_zhang
Expand
  • (Qingdao Branch of the Luoyang Ship Material Research Institute, Qingdao 266071, China

Received date: 2003-08-28

  Revised date: 2003-08-28

  Online published: 2003-08-28

摘要

应用正交实验设计 ,开发并研究了LY1 2铝合金 4价铈盐转化膜的成膜工艺及其膜层的耐蚀性能 .实验表明 :经稀土转化处理的铝合金其点蚀电位升高 ,自然腐蚀电位有所降低 ,从而降低了点蚀敏感性 ;试样极化阻力提高 70倍以上 ,耐蚀性能大大提高 ,与铬酸盐相当 ;另外 ,还结合电化学测试和表面分析 ,初步探讨了铝合金稀土转化膜的耐蚀机理

本文引用格式

王均涛 , 吴建华 , 陈光章 . 铝合金稀土转化膜成膜工艺研究[J]. 电化学, 2003 , 9(3) : 350 -356 . DOI: 10.61558/2993-074X.3319

Abstract

The orthogonal design was used to screen the film_forming technique on LY12 aluminum alloy using quadrivalent cerium salt, and the corrosion_resistance performance of the coating was studied. The results revealed that: after LY12 aluminum alloy was treated by cerium salt, its pitting potential shifts to positive direction while the corrosion potential slightly decreases, showing that the alloy becomes less sensitive to pitting corrosion was greatly improved, comparable to that after chromate treatment; in addition, by combining the results of electrochemical measurements with surface analysis, the mechanism of corrosion_resistance on the race_earth conversion coating of the aluminum alloy was also discussed.

参考文献

[1] JamesT ,RenshawJr.Aluminumpretreatment:nextgenerationnonchrometechnologiesarereadyforthenewmillennium[J].MetalFinishing,1997,12:28~31. [2] Keda,Meguro.Surfacetreatmentchemicalsandbathforaluminumoritsalloyandsurfacetreatmentmethod[P].E .U .Patent:No.0411606A2,1990_01_08. [3] DanilidisI ,SykesJM ,HuntersJA ,etal.Manganesebasedconversiontreatment[J].SurfaceEngineer,1999,15(5):401~405. [4] HintonBRW ,ArnottDR ,RyanNE .Ceriumconversioncoatingsforthecorrosionprotectionofaluminum[J].MetalForum,1986,9(3):162~173. [5] MansfeldF ,WangY ,ShihH .TheCe_Moprocessforthedevelopmentofastainlessaluminum[J].Electro chemicalActa.1997,37(12):2277~2282. [6] Mansfeldetal.Methodforcreatingacorrosion_resistantsurfaceonaluminumalloyshavingahighcoppercon tent[P].USPatent:No.5582654,1996_12_10. [7] ValerieGuillaumin,GeorgesMankowski.Localizedcorrosionof2024T351aluminumalloyinchloridemedia[J].CorrosionScience,1999,41:421~438.
文章导航

/