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研究论文

锂离子电池碳负极中的相互作用研究

  • 陈昌国 ,
  • 张洪敏 ,
  • 陈佳 ,
  • 余丹梅
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  • 重庆大学化学化工学院,重庆大学化学化工学院,重庆大学化学化工学院,重庆大学化学化工学院 重庆 400044 ,重庆 400044 ,重庆 400044 ,重庆 400044

收稿日期: 2004-02-28

  修回日期: 2004-02-28

  网络出版日期: 2004-02-28

The Interaction in Doping Lithium of Carbonaneous Anode in Lithium Ion Battery

  • CHEN Chang-guo~ ,
  • ZHANG Hong-min ,
  • CHEN Jia ,
  • YU Dan-mei
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  • (College of Chemistry & Chemical Engineering,Chongqing University,Chongqing 400044,China

Received date: 2004-02-28

  Revised date: 2004-02-28

  Online published: 2004-02-28

摘要

应用量子化学DV_Xα方法对储锂的单锂嵌套模型,LiC6模型,LiC2模型进行计算.分析电荷密度差值图发现锂离子在碳材料中有"吸"电子效应,其所得电子一般来自它所正对的苯环碳平面.计算表明,石墨插层化合物LiC6能够稳定存在,而LiC2则较难稳定存在.

本文引用格式

陈昌国 , 张洪敏 , 陈佳 , 余丹梅 . 锂离子电池碳负极中的相互作用研究[J]. 电化学, 2004 , 10(1) : 46 -50 . DOI: 10.61558/2993-074X.1544

Abstract

The quantum chemical DV-X_α method was used to calculate the lithium-doped models from one-Li-dopant to LiC_6 and LiC_2. It was found that Li~+ has an tendency to attract electrons from the carbon plane through the C_6 hexagons lying above or below it by the graph of charge-density difference. It was shown that LiC_6 can exist steadily,while LiC_2 can not exist steadily.

参考文献

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