欢迎访问《电化学(中英文)》期刊官方网站,今天是
研究论文

液流电池研究进展

  • 董全峰
展开
  • 厦门大学化学系,中国科学院大连化学物理研究所燃料电池工程中心,厦门大学化学系,厦门大学化学系,厦门大学化学系,厦门大学化学系,厦门大学化学系 厦门大学宝龙电池研究所固体表面物理化学国家重点实验室福建厦门361005 ,辽宁大连116023 ,厦门大学宝龙电池研究所固体表面物理化学国家重点实验室福建厦门361005 ,厦门大学宝龙电池研究所固体表面物理化学国家重点实验室福建厦门361005 ,厦门大学宝龙电池研究所固体表面物理化学国家重点实验室福建厦门361005 ,厦门大学宝龙电池研究所固体表面物理化学国家重点实验室福建厦门361005 ,厦门大学宝龙电池研究所固体表面物理化学国家重点实验室福建厦门361005

收稿日期: 2005-08-28

  修回日期: 2005-08-28

  网络出版日期: 2005-08-28

Research Progresses in a Flow Redox Battery

  • DONG Quan-feng~
Expand
  • (*1), ZHANG Hua-min~(2), JIN Ming-gang~(1), ZHENG Ming-sen~(1), ZHAN Ya-ding, SUN Shi-gang~(1), LIN Zu-geng~(1)(1. State Key Lab for Physical Chemistry of Solid Surface and Xiamen Univ.-PowerLong Battery Institute, Department of Chemistry , Xiamen University, Xiamen 361005, China ,2.Fuel cell R & D Center,Dalian Institute of Chemical Physics,Chinese Academy of Science,Dalian 116023,China

Received date: 2005-08-28

  Revised date: 2005-08-28

  Online published: 2005-08-28

摘要

和通常熟悉的以固体或气体材料作电极的化学电源不同,液流电池的活性物质是流动着的电解质溶液,是一种可实现规模化储能的电化学装置.本文简要综述液流电池的发展历史及其研究现状,瞻望发展前景,并提出它存在的主要问题.

本文引用格式

董全峰 . 液流电池研究进展[J]. 电化学, 2005 , 11(3) : 237 -243 . DOI: 10.61558/2993-074X.1647

Abstract

As a large scale electrochemical storage device, flow redox battery in which the active materials are flowing electrolytes is different from the common batteries employing solid or gas materials as an electrode. In this paper we introduced flow redox battery in brief, reviewed its development and actual state on (study). The main problem existed in the new device was discussed when viewed with its future developments.

参考文献

[1]Business Commun ications Company,Inc.Large andAdvanced Battery Technology and M arkets[EB/OL].http://www.giich inese.com/ch inese/bc24077_large_battery_toc.htm l [2]Thaller L H,N ice A W.F lu id battery prom ises econom-ical storage[J].Power Engineering,1981,85(2):56~58. [3]Thaller L H.E lectrically Rechargeab le Redox F lowCells[C].San Franc isco,USA:SAE Preprints,749142,1974.924. [4]Thaller L H.E lectrically rechargeab le redox flow cells[P].US Pat:3996064,1974. [5]Stalnaker D K,L ieberm an A.Design and Assemb lyConsiderations for Redox Cells and Stacks[M].Oh io,USA:NASA Tech M emo,1981.10. [6]Hagedorn N H,Haaller L H.Design flexib ility of redoxflow system s[A].Proceed ings of the Intersoc iety En-ergy Conversion Engineering Conference[C].Los An-geles,USA:IEEE,New York,1982.2:600. [7]Nozak i K,Ozawa T.Research and developm ent of red-ox-flow battery in electrotechn ical laboratory[A].Pro-ceed ings of the Intersoc iety Energy Conversion Engi-neering Conference[C].Los Angeles,USA:IEEE,New York,1982.2:610. [8]Anon.M ajor reduction in electric energy storage costs[J].Industrial Research&Developm ent,1980,22(3):97~98. [9]Nozak i K,Kaneko H,Ozawa T.Prospect of electric en-ergy storage by secondary batteries[J].C ircu lars ofthe E lectrotechn ical Laboratory,1979,54(201):71. [10]Sakamoto T,Mori N,Kuno M,et al.Developm ent ofredox flow battery[J].Sum itomo E lectric Techn icalReview,1989,28:180. [11]Fang B,Iwasa S,W e i Y,et al.A study of the Ce(III)/Ce(IV)redox coup le for redox flow battery ap-p lication[J].E lectroch im ica Acta,2002,47(24):3 971~3 976. [12]Yam amura T,Sh iokawa Y,Yam ana H,et al.E lectro-chem ical investigation of uran ium-βd iketonates for all-uran ium redox flow battery[J].E lectroch im ica Acta,2002,48(1):43~50. [13]Trainham J A,Newm an J.Comparison between flow-through and flow-by porous electrodes for redox energystorage[J].E lectroch im ica Acta,1981,26(4):455~469. [14]Savinell R F,L iu C C,Ch iang S H,et al.Investiga-tion of a parallel p late iron-titan ium redox electrochem-ical cell[A].Proceed ings-The E lectrochem ical Soc i-ety[C].Boston,M ass:E lectrochem Soc Inc,Prince-ton,NJ,1979.79(1):468. [15]W ang Y Y,L in M R,W an C C.Study of the d is-charge perform ance of the Ti/Fe redox flow system[J].Journal of Power Sources,1984,13(1):65~74. [16]Anon.F lu id battery prom ises to store electric ity at low-er cost for power-generation system s[J].Power,1979,123(7):83~88. [17]Gahn R F,Hagedorn N H,Johnson J A.Cyc ling Per-form ance of the Iron-chrom ium Redox Energy StorageSystem[M].C leveland,Oh,USA:NASA Techn icalM emorandum,NASA,1985.18. [18]Sh im ada M,Tsuzuk i Y,L izuka Y,et al.Investigationof the aqueous Fe-Cr redox flow cell[J].Chem istryand Industry,1988,3:80~82. [19]Adam s G B,Hollandsworth R P,L ittauer E L.Re-chargeab le alkaline zinc/ferricyan ide hybrid redox bat-tery[C].Proceed ings of the Intersoc iety Energy Con-version Engineering Conference[A].Atlanta,Ga,USA:ASME,New York,1981.1:812. [20]Kondo S,M isak i H,Suzuk i S.Developm ent of ad-vanced battery electric energy storage system for elec-tric utility load leveling[A].Proceed ings of the Inters-oc iety Energy Conversion Engineering Conference[C].M iam i Beach,FL,USA:SAE(P-164),W arrendale,PA,USA,1985.11. [21]Rychc ik M,Skyllas K M.Characteristics of a new all-vanad ium redox flow battery[J].Journal of PowerSources,1988,22(1):59~67. [22]Sum E,Skyllas K M.Study of the V(ii)/V(iii)redoxcoup le for redox flow cell app lications[J].Journal ofPower Sources,1985,15(2-3):179~190. [23]Skyllas K M,Rychc ik M,Rob ins R G,et al.New all-vanad ium redox flow cell[J].Journal of the E lectro-chem ical Soc iety,1986,133(5):1 057~1 058. [24]Fang B,Iwasa S,W e i Y,et al.A study of the Ce(III)/Ce(IV)redox coup le for redox flow battery ap-p lication[J].E lectroch im ica Acta,2002,47:3 971~3 976. [25]Skyllas K M.Novel vanad ium chloride/polyhalide red-ox flow battery[J].Journal of Power Sources,2003,124(1):299~302. [26]M i C H,X ia X,Zhang X G.E lectrochem ical behav-iors of Mn3+/Mn2+system in redox flow battery[J].D ianyuan Jishu/Ch inese Journal of PowerSources,2003,27(1):2. [27]M atsuda Y,Tanaka K,Okada M,et al.Rechargeab leredox battery utilizing ruthen ium comp lexes w ith non-a-queous organ ic electrolyte[J].Journal of App lied E-lectrochem istry,1988,18(6):909~914. [28]Yam amura T,Sh iokawa Y,Yam ana H,et al.E lectro-chem ical investigation of uran ium-βd iketonates for all-uran ium redox flow battery[J].E lectroch im ica Acta,2002,48(1):43~50. [29]Pau lenova A,Creager S E,Navratil J D,et al.Redoxpotentials and k inetics of the Ce3+/Ce4+redox reac-tion and solub ility of cerium su lfates in su lfuric ac id so-lutions[J].Journal of Power Sources,2002,109(2):431~438. [30]Ohya H,Emori K,Ohto T,et al.Ion-selective M em-branes forRedox-flow Battery[C].New York:P lenumPress,1986.273~280. [31]D rioli E,Nakagak i M.M embranes and m embraneprocesses(proceed ings of the first europe-japan con-gress)[C].New York:P lenum Press,1986.663. [32]R itch ie IM,S iira O T.Redox batteries-an overview[M].Oxford,Engl:Pergamon Press,1984.1 732~1 737. [33]Hagedorn N H.Nasa redox storage system developm entproject[J].NASA Techn ical M emorandum,1984:46. [34]F inklea H O.M easurem ent ofm ass-transfer param etersthrough a polym er coating by chronoamperom etry[J].E lectrochem ical Soc iety Extended Abstracts,1984,48(2):931~932. [35]Arnold C J,Assink R A.Developm ent of su lfonatedpolysu lfone m embranes for redox flow batteries[J].Journal ofM embrane Sc ience,1988,38(1):71~83. [36]Mohamm ad i T,Skyllas K M.Preparation of su lfonatedcomposite m embrane for vanad ium redox flow batteryapp lications[J].Journal ofM embrane Sc ience,1995,107(1~2):35. [37]Hwang G J,Ohya H.Crosslink ing of an ion exchangem embrane by accelerated electron rad iation as a sepa-rator for the all-vanad ium redox flow battery[J].Jour-nal ofM embrane Sc ience,1997,132(1):55~61. [38]Ohya H,Kuromoto M,M atsumoto H,et al.E lectricalresistivities and perm eab ilities of composite m embranesbased on a cation exchange m embrane for a redox flowbattery[J].Journal ofM embrane Sc ience,1990,51(1~2):201~214. [39]W iedem ann E,He intz A,L ichtenthaler R N.Trans-port properties of vanad ium ions in cation exchangem embranes:Determ ination of d iffusion coeffic ients u-sing a d ialysis cell[J].J.of M embrane Sc ience,1998,141:215~221. [40]Mohamm ad i T,Skyllas K M.Characterisation of novelcomposite m embrane for redox flow battery app lications[J].Journal of M embrane Sc ience,1995,98(1~2):77. [41]Ogum i Z,Uch imoto Y,Tsu jikawa M,et al.Enhance-m ent of proton selective of cation exchange m embraneby p lasm a mod ification[J].Journal of the E lectro-chem ical Soc iety,1989,136(4):1 247~1 248. [42]Ogum i Z,Uch imoto Y,Tsu jikawa M,et al.Mod ifica-tion of ion exchange m embrane surface by p lasm aprocess.I.H+ion perm-selective m embrane from na-fion for redox-flow battery[J].Journal of the E lectro-chem ical Soc iety,1990,137(5):1 430~1 435. [43]Ch ieng S C,KazacosM,Skyllas K M.Mod ification ofDaram ic,m icroporous separator,for redox flow batteryapp lications[J].Journal ofM embrane Sc ience,1992,75(1~2):81~91. [44]Mohamm ad i T,Skyllas K M.Mod ification of an ion-ex-change m embranes for vanad ium redox flow battery ap-p lications[J].Journal of Power Sources,1996,63(2):179~186. [45]Sukkar T,Skyllas K M.Mod ification ofm embranes u-sing polyelectrolytes to improve water transfer proper-ties in the vanad ium redox battery[J].Journal ofM embrane Sc ience,2003,222(1~2):249~264. [46]O riji G,Katayam a Y,M iura T.Investigations on V(IV)/V(V)and V(II)/V(III)redox reactions byvarious electrochem icalm ethods[J].Journal of PowerSources,2005,139:321~324. [47]Skyllas K M,L im antari Y.K inetics of the chem icald issolution of vanad ium pentoxide in ac id ic brom ide so-lutions[J].Journal of App lied E lectrochem istry,2004,34(7):681~685. [48]W u H,Selm an J R,Hollandsworth R P.M ass transferand current d istribution in a zinc/redox-battery flowcell[J].Ind ian Journal ofTechnology,1986,24(7):372~380. [49]Homm a T,Zhao G,Ohsawa Y.Theoretical stud ies oncharge and d ischarge characteristics of redox flow bat-tery[J].E lectrical Engineering in Japan,1990,110(4):24~34. [50]He intz A,Illenberger C.D iffusion coeffic ients of B r2in cation exchange m embranes[J].Journal of M em-brane Sc ience,1996,113(2):175~181. [51]Rosaria F,Abraham D S,Thom as D C,et al.M em-braneless vanad ium redox fuel cell using lam inar flow[J].J.AM.CHEM.SOC.,2002,124:12 930~12931.
文章导航

/