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研究论文

锂离子电池硅化物及其复合负极材料的研究

  • 闫俊美
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  • 厦门大学固体表面物理化学国家重点实验室厦门大学化学系,厦门大学固体表面物理化学国家重点实验室厦门大学化学系,厦门大学固体表面物理化学国家重点实验室厦门大学化学系,厦门大学固体表面物理化学国家重点实验室厦门大学化学系 福建厦门361005,厦门大学环境科学研究中心,福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005

收稿日期: 2005-11-28

  修回日期: 2005-11-28

  网络出版日期: 2005-11-28

Silicides and Composites Materials as Anodes for Lithium Ion Batteries

  • YAN Jun-mei~
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  • (1,2),HUANG Hui-zhen~(1),ZHANG Jing~(1),YANG Yong~(*1)(1.State Key Laboratary for Physical Chemistry of Solid Surface,Department of Chemistry,Xiamen University,Xiamen 361005,China,2.Cencer for Environmental Science research of Xiamen University,Xiamen 361005,China

Received date: 2005-11-28

  Revised date: 2005-11-28

  Online published: 2005-11-28

摘要

应用机械合金退火法合成Mg2S i及MnS i材料,并由机械球磨法制备系列Mg2S i/C复合材料.电化学性能研究表明:以硅化物与碳材料复合,即可明显提高原纯硅化物材料的可逆比容量及其循环稳定性,而球磨复合法则是实现硅化物材料复合的一种简单且有效方法.

本文引用格式

闫俊美 . 锂离子电池硅化物及其复合负极材料的研究[J]. 电化学, 2005 , 11(4) : 416 -419 . DOI: 10.61558/2993-074X.1679

Abstract

The anode materials of Mg_(2)Si and MnSi were synthesized by mechanically activated annealing(MAA) techniques in this work and the in electrochemical performances were also studied.A series of composite materials of Mg_(2)Si and CNTs or CMS were prepared by ball-milling method respectively.The reversible capacities of the composites were higher than that of the pure Mg_(2)Si and pure carbon materials.The cyclic performances have been improved greatly by ball-milling of the Mg_(2)Si and carbon materials.Results show that ball-milling method is one kind of method to make alloy materials into practical use.

参考文献

[1]Roberts G A,Cairns E J,Re im er J A.M echan ism oflith ium insertion into m agnesium silic ide[J].Journal ofthe E lectrochem ical Soc iety,2004,151(4):A493. [2]Moriga T,W atanabe K,Tsu ji D,et al..Reactionm echan ism of m etal silic ide Mg2S i for L i insertion[J].Journal of Solid State Chem istry,2000,153:386. [3]K im H,Choi J,Sohn H J,et al.The insertionm echa-n ism of lith ium intoMg2S i anode m aterial for L i-Ion bat-teries[J].Journal of the E lectrochem ical Soc iety,1999,146(12):4 401. [4]W olfenstine J.CaS i2as an anode for lith ium-ion batter-ies[J].Journal of Power Sources,2003,124:241. [5]Poizot P,Laruelle S,G rugeon S,et al.Nano-sizedtransition-m etal oxides as negative-electrode m aterialsfor lith ium-ion batteries[J].Nature,2000,407:496~499. [6]N ish ijim a M,Kagohash i T,Takeda Y,et al.E lectro-chem ical stud ies of a new anode m aterial,L i3-xMNx(M=Co,N i,Cu)[J].J.Power Sources,1997,68(2):510~514. [7]Shodai T,Okada S,Tob ish im a S,et al.Study of L i3-xMxN(M:Co、N i or Cu)system for use as anode m ateri-al in lith ium rechargeab le cells[J].Solid State Ion ics,1996,86~88:785~789. [8]W ang G.X,Choi J,Sohn H J,et al.G raph ite-tincomposites as m aterials for lith ium-ion batteries[J].Journal of Power Sources,2001,97~98:211. [9]D imov N,Kugino S,Yosh io A.M ixed silicon-graph itecomposites as anode m aterial for lith ium ion batteries in-fluence of preparation cond itions on the properties of them aterial[J].J.Power Sources,2004,136(1):108~114. [10]Yang J,W ang B F,W ang K,et al.,S i/C compositesfor h igh capac ity lith ium storage m aterials[J].E lectro-chem ical and Solid-State Letters,2003,6(8):A154~A156. [11]W en Z S,Yang J,W ang B F,et al.H igh capac itysilicon/carbon composite anode m aterials for lith iumion batteries[J].E lectrochem istry Commun ications,2003,5(2):165~168.
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