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研究论文

纳米镁储氢材料吸放氢动力学性能的研究进展

  • 墨伟 ,
  • 孙洪亮 ,
  • 张海昌 ,
  • 杨化滨 ,
  • 周作祥
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  • 南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所 天津300071,天津300071,天津300071,天津300071,天津300071

收稿日期: 2006-02-28

  修回日期: 2006-02-28

  网络出版日期: 2006-02-28

Development on Hydriding/Dehydriding Kinetics of Mg Nano-materials for Hydrogen Storage

  • MO Wei ,
  • SUN Hong-Liang ,
  • ZHANG Hai-chang ,
  • YANG Hua-bin~ ,
  • ZHOU Zuo-xiang
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  • (Institute of New Energy Material Chemistry,Nankai University,Tianjin 300071,China

Received date: 2006-02-28

  Revised date: 2006-02-28

  Online published: 2006-02-28

摘要

综述近十年来国内外有关纳米镁储氢材料吸放氢动力学的研究现状和发展趋势.众多研究表明,应用高能球磨法制备纳米镁复合储氢材料,并以过渡金属氧化物为催化剂,或者用ABx型储氢合金与镁复合,都能显著改善镁的吸放氢动力学性能.

本文引用格式

墨伟 , 孙洪亮 , 张海昌 , 杨化滨 , 周作祥 . 纳米镁储氢材料吸放氢动力学性能的研究进展[J]. 电化学, 2006 , 12(1) : 9 -15 . DOI: 10.61558/2993-074X.1689

Abstract

The development of Mg nano-materials for hydrogen storage in the recent decade has been reviewed in this paper.It was shown the Mg nano-powders prepared by high-energy ball milling showed promising hydriding and dehydriding performance with the transition metal oxides and other types of hydrogen storage alloys(ABx)as the catalysts.

参考文献

[1]Schlapbaah L,Zuttel A.Hydrogen storage m aterials formob ile app lications[J].Nature,2001,414:353. [2]Yang Huab in(杨化滨).Research on the characteristicsof the ternary Mg2N i0.75M0.25system[D].Tian jin:Nan-kai Un iversity,2000. [3]Yuan Huatang,Yang Huab in,Zhou Zuoxiang,et al.Pressure-composition isotherm s of the Mg2N i0.75Fe0.25-Mg system synthesized by rep lacem ent-d iffusion m ethod[J].J.A lloys Comp.,1997,260:256. [4]Yang Huab in(杨化滨),Zhang Haichang(张海昌),Zhou zuoxiang(周作祥).Corrosion behavior of Mg1.85Mm0.15-N i hydrogen storage alloys mod ified by electro-less Cu in CH3OH-H2O solutions[J].E lectrochem istry(in Ch inese),2003,9(2):196. [5]YANG H B,SUN H,YANG ED,et al.The corrosionbehavior of ternaryMg2-xMmxN i alloys[J].J.E lectro-chem.Soc.,2002,149(5):A543. [6]Gao Xuep ing(高学平),LU Zh iwe i(卢志威),ZhangHuan(张欢),et al.Hydrogen storage m aterials andm etal hydride-N i batteries[J].Physics(in Ch inese),2004,33(3):170. [7]Zaluska A,Zalusk i L,Str m-O lsen J O.Nanocrystallinem agnesium for hydrogen storage[J].J.A lloys Comp.,1999,288:217. [8]Gennari F C,Castro F J,Urretavizcaya G.Hydrogen de-sorption behavior from m agnesium hydrides synthesizedby reactive m echan ical alloying[J].J.A lloys Comp.,2001,321:46. [9]Zaluska A,Zalusk i L,Strm-O lsen J O.Structure,catal-ysis and atom ic reactions on the nano-scale:a system aticapproach to m etal hydrides for hydrogen storage[J].App lied Physics A,2001,72:157. [10]Züttel A.M aterials for hydrogen storage[J].M ateri-als today,2003:September,24. [11]Oelerich W,K lassen T,Borm ann R.Hydrogen sorptionof nanocrystalline Mg at reduced temperatures by m et-al-oxide catalysts[J].Adv.Eng.M ater.,2001,3:487. [12]Oelerich W,K lassen T,Borm ann R.M etal odes.cata-lysts for improved hydrogen sorption in nanocrystallineMg-based m aterials[J].J.A lloys Comp.,2001,315:237. [13]Dehouche Z,K lassen T,Oelerich W.et al.Cyc ling,and therm al.stab ility of nanostructured MgH2-Cr2O3composite for hydrogen storage[J].J.A lloys Comp.,2002,347:319. [14]Yu Zhenxing(于振兴),W ang Erde(王尔德),L iuZuyan(刘祖岩),et al.Properties of hydrid ing and de-hydrid ing of nanocrystalline composite ofMg2N i-Cr2O3[J].Ch inese Journal of Nonferrous M etals,2002,12(4):743. [15]Castro F J,Bobet J L.Hydrogen sorption properties ofan Mg+WO3m ixture m ade by m echan ical alloying[J].J.A lloys Comp.,2004,366:303. [16]Bobet J L,Kraw iec S D,G rigorova E,et al.Add ition ofnanosized Cr2O3to m agnesium for improvem ent of thehydrogen sorption properties[J].J.A lloys Comp.,2003,351:217. [17]Song M Y,Bobet J L,Darriet B.Improvem ent in hy-drogen sorption properties ofMg by reactive m echan icalgrind ing w ith Cr2O3,A l2O3and CeO2[J].J.A lloysComp.,2002,340:256. [18]Oelerich W,K lassen T,Borm ann R.Comparison of thecatalytic effects of V,V2O5,VN and VC on the hydro-gen sorption of nanocrystalline Mg[J].J.A lloysComp.,2001,322:115. [19]W ang Erde(王尔德),Yu Zhenxing(于振兴),L iu Zuy-an(刘祖岩).Hydorgen storage properties of nanocom-posite Mg2N i-V2O5[J].Functional M aterial,Ch ina.2002,33(3):280. [20]Barkhoudarian G,K lassen T,Borm ann R.Fast hydro-gen sorption k inetics of nanocrystalline Mg using Nb2O5catalyst[J].Scripta M ater.,2003,49;213. [21]Barkhoudarian G,K lassen T,Borm ann R.E ffect ofNb2O5content on hydrogen reaction k inetics ofMg[J].J.A lloys Comp.,2004,364;242. [22]KhrussanovaM,TerzievaM,Peshey P,et al.Hydrid ingof m echan ically alloyed m ixtures of m agnesium w ithMnO2,Fe2O3and N iO[J].M at.Res.Bu ll.,1991,26:561. [23]Kwon IH,Bobet J L,Bae JS,et al.Improvem ent of hy-drogen-storage properties ofMg by reactive m echan icalgrind ing w ith Fe2O3[J],J.A lloys Comp.,2005,396:264. [24]SongM Y,Hong S H,Kwon IH,et al.Improvem ent ofhydrogen-storage properties ofMg by reactive m echan i-cal grind ing w ith Fe2O3prepared by spray conversion[J].J.A lloys Comp.,2005,398:283. [25]SongM Y,Kwon I H,Kwon S N,et al.Preparation ofhydrogen-storage alloyMg 10 wt.%Fe2O3under vari-ous m illing cond itions[J].Int.J.Hydrogen Energy,2006,31:43. [26]Terzieva M,Khruesanova M,Peshev P.Hydrid ing andehydrid ing characterisitics ofMg-LaN i5composite m a-terials prepared by m echan ical alloying[J].J.A lloysComp.,1998,267:235. [27]L iang G.,Boily S,Huot J,et al.Hydrogen absorptionproperties of a m echan ically m illed Mg-50wt.%LaN i5composite[J].J.A lloy Comp.,1998,268:302. [28]L iang G,Huot J,Boily S,et al.Hydrogen storage inm echan ically m illed Mg LaN i5and MgH,LaN i5com-posites[J].J.A lloys Comp.,2000,297:261. [29]M andal P,Srivastava 0 N.Hydrogenation behaviour of-ten composite storage m aterialMg-x%FeTi[J].J.A l-loys Comp.,1994,205:111. [30]Kondo T,Sh indo K,Arakawa M.M icrostructure andhydrogen absorption desorption properties of MgTiFe0.92Mn0.08composites prepared by wet m echan icalm illing[J].J.A lloys Comp.,2004,375:283. [31]L iang G.X.,W ang E D,Fang S S.Hydrogen absorp-tion and desorption characteristics of m echan icallym illed Mg-35wt.%FeTi1.2powders[J].J.A lloysComp.,1995,223:111. [32]W ang P,W ang A M,D ing B Z,et al.Mg FeTi1.2(a-morphous)composite for hydrogen storage[J].J.A l-loys Comp.,2002,334:243. [33]Zaluska A,Zalusk i L,Strm-O lsen J O.Synergy of hy-drogen sorption in ball-m illed hydrides ofMg and Mg2N i[J].J.A lloys Comp.,1999,289:197.
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