以电沉积铜为探针,循环伏安法研究硬脂酸钠在蓖麻油/水界面上自组装的动力学.在涂有蓖麻油的石墨粉-环氧树脂固态电极上,硬脂酸钠自组装膜形成过程可由电沉积铜阳极峰监测,遵从高斯函数生长动力学,生长速率常数为km=0.0006292(±0.0000294)s-1.硬脂酸钠自组装膜能较好地控制铜粒子的球形生长和生长尺度,形成硬脂酸钠自组装-铜纳米粒子复合膜.铜粒子在石墨粉-环氧树脂固态电极上为半球形生长,而在涂油和自组装电极上为球形生长.与蓖麻油涂层相比,石墨粉-环氧树脂固态电极与沉积铜间存在弱相互作用(ΔG0=3.86kJ/mol),而硬脂酸钠羧基与沉积铜也有较弱的相互作用(ΔG0=-2.412kJ/mol).

The self assembly membrane(SAM)formation kinetics of sodium stearate at castor oil/water interface was studied by cyclic voltammetrry.At caster oil coated graphite-epoxy solid electrode surface,the SAM grows according to the Gaussian growth function with a rate constant of km=0.0006292(0.0000294)s-1,and maximum particle size at t0=3127s.The SAM of sodium stearate controls the growth and particle size of the deposited copper nano particles well,and forms a composite membrane of the SAM and copper nano particle.The growth mechanism of copper particle at oiled electrode or SAM modified oiled electrode is spherical growth,while it is the semi-spherical growth at bared graphite-epoxy solid phase electrode.Compared with castor oil coated electrode,the deposited copper particles show the stronger interaction to graphite-epoxy solid phase electrode surface with the free energy change of ΔG0 = 3.86 kJ/mol and a weaker interaction to the SAM of sodium stearate with the free energy change of ΔG0=-2.412 kJ/mol.