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研究论文

质子交换膜燃料电池MnO_2-Pt/C复合催化剂阴极的富氧作用

  • 徐洪峰 ,
  • 张茂锋 ,
  • 甘全全 ,
  • 黄才胜
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  • 大连交通大学环境与化学工程学院,大连交通大学环境与化学工程学院,大连交通大学环境与化学工程学院,大连交通大学环境与化学工程学院 辽宁大连116028,辽宁大连116028,辽宁大连116028,辽宁大连116028

收稿日期: 2007-08-28

  修回日期: 2007-08-28

  网络出版日期: 2007-08-28

Oxygen Enrichment Effect of MnO_2-Pt/C Compound Catalyst to the Cathode of PEMFC

  • XU Hong-feng ,
  • ZHANG Mao-feng ,
  • GAN Quan-quan ,
  • HUANG Cai-sheng
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  • (Department of Enviroment and Chemical Engineering,Dalian Jiao-tong University,Dalian 116028,Liaoning,China

Received date: 2007-08-28

  Revised date: 2007-08-28

  Online published: 2007-08-28

摘要

质子交换膜燃料电池空气电极阴极催化剂的富氧作用是提高其性能的关键.应用化学氧化法制备MnO2-Pt/C复合催化剂,研究MnO2的富氧作用,应用CV、CP、TEM等方法表征该催化剂,并组装成单电池测试其性能.

本文引用格式

徐洪峰 , 张茂锋 , 甘全全 , 黄才胜 . 质子交换膜燃料电池MnO_2-Pt/C复合催化剂阴极的富氧作用[J]. 电化学, 2007 , 13(3) : 316 -319 . DOI: 10.61558/2993-074X.1829

Abstract

TO study of the oxygen storage material of air cathode is crucial for increasing performance of proton exchange membrane fuel cell.Using the MnO2 as oxygen storage materials,a MnO2-Pt/C catalysts were prepared and is used to replace the conventional Pt/C in air cathode.The electrochemical performance of air cathode composed of MnO2 supported on Pt/C and the properties of fuel cell composed of MnO2-Pt/C were investigated by using the CV,galvanostatic dischange method and TEM.

参考文献

[1]XU Hongfeng(徐洪峰).YI Baolian(衣宝廉),HANMing(韩明).Effect of electrode~on the performanceof proton exchange membrane fuel cell[J].ChineseJournal of Power Sources(in Chinese),1998,22(4):163-166. [2]XU Zhiqiang,QI Zhigang,Arthur Kaufman.Effect ofoxygen storage materials on the performance of proton-exchange membrane fuel cells[J].Journal of PowerSources,2003,115:40-43. [3]He H,Dai H X,Au C T.Defective structure,oxygenmobility,oxygen storage capacity,and redox propertiesof RE-based(RE=Ce,Pr)solid solutions[J].CatalysisToday,2004,90:245-254. [4]Yuta Nabae,Ichiro Yamanaka,Kiyoshi Otsuka.Elec-tro-catalysis of the Cu/carbon cathode for the reductionof O2during fuel-cell reactions[J].Applied CatalysisA:General,2005,280:149-155. [5]Hwan Bae Yu,Joon-Hee Kim,Ho-In Lee,et al.De-velopment of nanophase CeO2-Pt/C cathode catalyst fordirect methanol fuel cell[J].Journal Power Sources,2005,140:59-65. [6]Nalini P Subramanian,Swaminatha P Kumaraguru,Hector Colon-Mercado,et al.Studies on Co-based cata-lysts supported on modified carbon substrates for PEMFCcathodes[J].Journal of Power Sources,2005,112:131-137.
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