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研究论文

酞菁配合物对锂-亚硫酰氯电池正极的催化作用

  • 许占位 ,
  • 孙庆津 ,
  • 苏碧云 ,
  • 车兔林 ,
  • 宋艳虹 ,
  • 李要民 ,
  • 赵建社
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  • 西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西北大学化学系陕西省物理无机化学重点实验室,西安机电信息研究所,西北大学化学系陕西省物理无机化学重点实验室 陕西西安710069,陕西西安710069,陕西西安710069,陕西西安710069,陕西西安710069,陕西西安710065,陕西西安710069

收稿日期: 2007-08-28

  修回日期: 2007-08-28

  网络出版日期: 2007-08-28

Studies on Catalytic Mechanism of Li/SOCl_2 Batteries by Metal Phthalocyanine Complexes

  • XU Zhan-wei ,
  • SUN Qing-jin ,
  • SU Bi-yun ,
  • CHE Tu-lin ,
  • SONG Yan-hong ,
  • LI Yao-min ,
  • ZHAO Jian-she
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  • (1.Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,2.P.O.Box 121,Xi'an,710065,China

Received date: 2007-08-28

  Revised date: 2007-08-28

  Online published: 2007-08-28

摘要

合成过渡金属酞菁配合物MPc(M=Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ)),研究MPc及其中心离子对L i/SOC l2电池正极的催化作用,并提出相关催化机理.

本文引用格式

许占位 , 孙庆津 , 苏碧云 , 车兔林 , 宋艳虹 , 李要民 , 赵建社 . 酞菁配合物对锂-亚硫酰氯电池正极的催化作用[J]. 电化学, 2007 , 13(3) : 293 -296 . DOI: 10.61558/2993-074X.1825

Abstract

Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.

参考文献

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