联用电化学阳极氧化和湿化学法制备氮掺杂的TiO2纳米管阵列膜.应用SEM、XPS、DRS分析、表征,并研究该膜层的形貌、组成和光学性质以及在卤钨灯照射下降解甲基橙水溶液的光电催化活性.结果表明:氮以取代掺杂的形式进入TiO2晶格,掺氮的TiO2纳米管阵列在可见光区有较强的吸收,其光电催化性能优于纯的TiO2纳米管阵列膜.
庄惠芳
,
赖跃坤
,
李静
,
孙岚
,
林昌健
. 氮掺杂TiO_2纳米管阵列的制备及其可见光光电催化活性研究[J]. 电化学, 2007
, 13(3)
: 284
-287
.
DOI: 10.61558/2993-074X.1823
Nitrogen-doped TiO2 nanotube array was fabricated by an electrochemical anodic oxidation followed a wet process.XPS result indicates that the nitrogen atoms were doped into lattice of TiO2 nanotubes.The UV-Vis spectra show that the photoabsorption of N-doped TiO2 nanotube array film is enhanced in the visible light region.Compared with the TiO2 nanotube array film,the N-doped TiO2 nanotubes exhibite a higher photocatalytic activity which is evaluated by the decomposition rate of methyl orange using the tungsten-halogen lamp as light source.
[1]Fujishima A,Rao T N,Trky D A.Titanium dioxidephotocatalysis[J].J Photochem Photobiol C-Photoche-mev,2000,1:1-21.
[2]Frank S N,Bard A J.Heterogeneous photocatalytic oxi-dation of cyanide ion in aqueous solution at TiO2powder[J].J Am Chem Soc,1977,99:303-304.
[3]Fujishima A,Zhang X.Titanium dioxide photocataly-sis:present situation and future approaches[J].Comptes Rendus Chim,2006,9:750-760.
[4]Asahi R,Morikawa T,Ohwaki T,et,al.Visible-lightphotocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293:269-271.
[5]Khan S U M,Al-Shahry M,Ingler Jr W B.Efficientphotochemical water splitting by a chemically modifiedn-TiO2[J].Science,2002,297:2243-2245.
[6]Saha N C,Tompkins H G.Titanium nitride oxidationchemistry:An x-ray photoelectron spectroscopy study[J].J Appl Phys,1992,72:3072-3079.
[7]LU Wen-lu(陆文璐),SHI Li-yi(施利毅),XIE Xiao-feng(谢晓峰),et al.Preparation and characterizationof nano-sized N-doped titania photocatalyst induced byvisible light[J].Journal of Shanghai University(Natu-ral Science Edition),2004,10(3):289-292.