六氰合铁酸锰铬修饰电极的制备及其电化学行为

张胜涛; 韩晓燕; 薛茗月

doi:10.61558/2993-074X.1833

电化学 >

2007 , Vol. 13 >Issue 3: 334 - 338

DOI: https://doi.org/10.61558/2993-074X.1833

研究论文

六氰合铁酸锰铬修饰电极的制备及其电化学行为

张胜涛 ,
韩晓燕 ,
薛茗月

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重庆大学化学化工学院,重庆大学化学化工学院,重庆大学化学化工学院重庆400044,重庆400044,重庆400044

收稿日期: 2007-08-28

修回日期: 2007-08-28

网络出版日期: 2007-08-28

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Preparation of Manganese/Chromium Hexacyanoferrate Modified Glassy Carbon Electrode and Its Electrochemical Behavior

ZHANG Sheng-tao ,
HAN Xiao-yan ,
XUE Ming-yue

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(College of Chemistry and Chemical Engineering,Chongqing University,Chongqing 400044,China

Received date: 2007-08-28

Revised date: 2007-08-28

Online published: 2007-08-28

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摘要

应用循环伏安法在活化玻碳电极(GCE)表面制备六氰合铁酸锰铬(MnCrHCF)膜修饰电极(MnCrH-CF/GCE)并研究其电化学性质.探讨影响膜电沉积的因素,研究pH值以及不同支持电解质等制备条件对该修饰电极性能的影响,优化制备工艺,分析其反应机理.

关键词： 玻碳电极; 六氰合铁酸锰铬; 循环伏安法

本文引用格式

张胜涛 , 韩晓燕 , 薛茗月 . 六氰合铁酸锰铬修饰电极的制备及其电化学行为[J]. 电化学, 2007 , 13(3) : 334 -338 . DOI: 10.61558/2993-074X.1833

Abstract

A film of poly(manganese/chromium hexacyanoferrate)(MnCrHCF)is formed on the glassy carbon electrode(GCE) by Cyclic Voltammetry scanning,and its electrochemical behavior was studied.Factors affecting the electro-deposition of the film such as pH values and sustaining electrolytes,were discussed.And mechanism of the reaction was investigated.

Key words： glassy carbon electrode; manganese/chromium hexacyanoferrate; cyclic voltammetry

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