由单质硫与碳纳米管合成一种新型含碳复合材料.XRD、SEM、BET比表面和孔径分布表征观察硫-碳纳米管复合材料,循环伏安法和电池充放电测试材料的电化学性能.结果表明:以硫-碳纳米管作正极组装的2016型扣式电池有较好的电化学性能,其初始放电比容量达680mAh/g(室温),30次循环放电比容量仍稳定在500mAh/g.
A carbon-containing composite was synthesized by heating element sulfur and carbon nanotubes. The sulfur-carbonnanotube composites were characterized by X-ray diffraction,SEM,Brunauer-Emmett-Teller.The electrochemical property was characterized by cyclic voltammetry,constant current charge and discharge.It was revealed that the sulfur-carbonnanotube cathode 2016-type coin cells exhibited a good electrochemical property with the initial dicharge specific capacity up to 680 mAh/g and a stable capacity approximately 500 mAh/g after 30 cycle numbers.
[1]Ho-Suk Ryu,Hyo-JunAhn,Ki-Won Kim,et al.Dis-charge behavior of lithium/sulfur cell with TEGDME based electrolyte at low temperature[J].J Power Sources,2006,163:201-206.
[2]Ho-Suk Ryu,Hyo-JunAhn,Ki-Won Kim,et al.Dis-charge process of Li/PVdF/S cells at room temperature[J].J Power Sources,2006,153:360-364.
[3]Bo Jin,Jong-Uk Kim,Hal-Bon Gu.Electrochemical properties of lithium-sulfur batteries[J].J Power Sources,2003,117:148-152.
[4]Xiujian Zhu,Zhaoyin Wen,Zhonghua Gu,et al.Elec-trochemical characterization and performance improve-ment of lithium/sulfur polymer batteries[J].J Power Sources,2005,139:269-273.
[5]Marmorstein D,Yu T H,Striebel K A,et al.Electro-chemical performance of lithium/sulfur cells with three different polymer electrolytes[J].J Power Sources,2000,89:219-226.
[6]Wang Jiuling,Yang Jun,Wan Chunrong,et al.Sulfur composite cathode materials for rechargeable lithium batteries[J].Adv Funct Mater,2003,13:487-492.
[7]He Xiangming,Pu Weihua,Wang Jiuling,el al.Sulfu-rization of polymers with elemental sulfur as cathode ma-terials for rechargeable lithium batteries[J].J Func-tional Polymers,2005,18(3):517-521.