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研究论文

锂硫二次电池硫-碳纳米管正极的合成和性能

  • 杜锐 ,
  • 袁中直
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  • 华南师范大学化学与环境学院;

收稿日期: 2009-08-28

  修回日期: 2009-08-28

  网络出版日期: 2009-08-28

Synthesis and Characterization of Sulfur-Carbonnanotubes as Cathode of Lithium/Sulfur Rechargeable Battery

  • DU Rui ,
  • YUAN Zhong-zhi
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  • (College of Chemistry and Environment,South China Normal University,Guangzhou Guangdong 510006,China

Received date: 2009-08-28

  Revised date: 2009-08-28

  Online published: 2009-08-28

摘要

由单质硫与碳纳米管合成一种新型含碳复合材料.XRD、SEM、BET比表面和孔径分布表征观察硫-碳纳米管复合材料,循环伏安法和电池充放电测试材料的电化学性能.结果表明:以硫-碳纳米管作正极组装的2016型扣式电池有较好的电化学性能,其初始放电比容量达680mAh/g(室温),30次循环放电比容量仍稳定在500mAh/g.

本文引用格式

杜锐 , 袁中直 . 锂硫二次电池硫-碳纳米管正极的合成和性能[J]. 电化学, 2009 , 15(3) : 284 -287 . DOI: 10.61558/2993-074X.1996

Abstract

A carbon-containing composite was synthesized by heating element sulfur and carbon nanotubes. The sulfur-carbonnanotube composites were characterized by X-ray diffraction,SEM,Brunauer-Emmett-Teller.The electrochemical property was characterized by cyclic voltammetry,constant current charge and discharge.It was revealed that the sulfur-carbonnanotube cathode 2016-type coin cells exhibited a good electrochemical property with the initial dicharge specific capacity up to 680 mAh/g and a stable capacity approximately 500 mAh/g after 30 cycle numbers.
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