在聚酯纤维基材及其织物表面,原位聚合形成厚度约1~2μm聚苯胺包覆层,制得聚苯胺(PANI)/聚酯(PET)导电织物.PANI层优异的导电性能使之成为有广阔发展前景的柔性电磁屏蔽材料.正交试验分析研究了苯胺单体浓度、氧化剂:苯胺摩尔比、掺杂酸浓度、反应时间对PANI包覆层外观形态、与基体结合牢度以及导电性的影响.实验表明:在经适当前处理的PET基材表面,以苯胺单体浓度为0.25mol/L、氧化剂与苯胺摩尔比为1∶1、掺杂酸浓度0.5 mol/L、反应时间60 min、反应温度为0~20℃时制备的PANI/PET导电织物方阻最小,导电性最好;掺杂酸酸性越强,导电性越好.SEM、FTIR及XRD测试表明涤纶织物表面有均匀连续的聚苯胺膜存在.分析表明聚苯胺分子链中氧化结构与还原结构含量基本相等,说明聚苯胺渗入纤维内部,使纤维无定形区面积增加,结晶度减小.
The formation of PANI coating on the surface of PET fiber and fabric was obtained by in-situ polymerization method.The coating′s thickness was about 1～2 μm.Orthogonal test methodology was used to analyze the main factors of preparation of PANI / PET conductive fabric.The effects of the aniline monomer concentration,oxidant: aniline molar ratio,doping acid concentration and types,reaction time on the conductivities of the fabric were studied.The structure of the polymer were characterized by SEM,FTIR and XRD.The results indicated that there was uniform and continuous polyaniline film on the surface of polyester fabric.The contents of oxidation and reduction of polyaniline molecular chain structure were basically the same.And the polyaniline infiltrated the fiber,so that amorphous area of the fiber increased and the crystallinity reduced.
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