三维三聚氰胺碳海绵/碘化钠复合材料作为钠离子电池正极材料的研究
收稿日期: 2025-01-08
修回日期: 2025-01-23
录用日期: 2025-03-05
网络出版日期: 2025-03-23
Three-Dimensional Melamine Carbon Sponge/NaI as Cathode Materials for Sodium-ion Batteries
Received date: 2025-01-08
Revised date: 2025-01-23
Accepted date: 2025-03-05
Online published: 2025-03-23
钠碘(Na-I)电池作为一种潜在的可替代锂离子电池的储能装置,展现出良好的发展前景。然而,其实际应用受到导电性差、热稳定性不足以及多碘化物溶解与穿梭效应的限制。在本研究中,我们报道了一种通过碳化商用三聚氰胺海绵制备碳海绵(MC)的新方法。所制备的MC具有独特的自生长碳纳米管结构,能够为多碘化物提供物理和化学吸附,从而有效改善Na-I2电池的电化学性能。实验结果表明,NaI/MC电极大幅降低了电化学阻抗,并减少了多碘化物的溶解效应。NaI/MC正极在200次循环测试中平均放电容量为92.75 mAh·g-1,同时库仑效率稳定维持在94%。本研究成果展示了在储能钠离子电池领域潜在的应用前景。
黄倩莹 , 刘悦 , 林子鑫 , 郑淑怡 , 梅婷婷 , 唐宇婷 , 张颖鹤 , 刘军 . 三维三聚氰胺碳海绵/碘化钠复合材料作为钠离子电池正极材料的研究[J]. 电化学, 2025 , 31(5) : 2501081 . DOI: 10.61558/2993-074X.3534
The sodium-iodine (Na-I) battery exhibits significant potential as an alternative energy storage device to the lithium-ion battery. However, its development is hindered by inadequate electrical and thermal stability, as well as the dissolution and shuttling of polyiodide. In this study, we report a preparation method for melamine carbon sponge (MC) via carbonizing a commercially available kitchen sponge. It was revealed that the as-prepared MC, composed of unique self-growing carbon nanotubes, could provide both physical and chemical adsorption capabilities for intermediate polyiodides to improve the electrochemical performance of NaI. Consequently, the NaI/MC electrode effectively minimized polyiodide dissolution and reduced the electrochemical impedance. The NaI/MC cathode demonstrated a high average discharge capacity of 92.75 mAh·g-1 over 200 cycles while maintaining a coulombic efficiency of 94%. The research findings from our study have promising applications in Na-I batteries.
Key words: sodium-iodine battery; sodium iodide; melamine carbon sponge
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